Robert A. Toth, "Line strengths (900–3600 cm−1), self-broadened linewidths, and frequency shifts (1800–2360 cm−1) of N2O," Appl. Opt. 32, 7326-7365 (1993)
Self-broadened linewidths and pressure-induced frequency shifts of N2O were measured from spectra obtained at high spectral resolution in the 1800–2630 cm−1 region. From measurements of 136 lines, the average pressure-shift coefficient was found to be −0.0015 ± 0.0006 cm−1/atm. The shift coefficients were found to have a weak J dependence, in which the magnitude of the coefficients increases with increasing values of J. Line-strength measurements were derived from spectra obtained at low sample pressures, and these data were analyzed to determine vibrational band strengths, rotationless dipole-moment matrix elements, and F factor coefficients for several bands in the 900–3600 cm−1 region. Measurements of over 15,000 selected vibration–rotation transitions, including eight N2O isotopic species, were used in the various analyses.
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Used in measurements of N2O self-broadened linewidths and collision-induced frequency line shifts.
Asterisk denotes lines used in analysis to determine smoothed values of self-broadening coefficients for the 446 molecule. Plus sign denotes lines used in analysis to determine smoothed values of the 448 molecule linewidth coefficients broadened by 446 molecules.
Table 3
Smoothed Values of Self-broadening Coefficients b∘ of N2O Derived from Measurements
b∘ in cm−1 × 104; measurements taken at 296 K.
Values given in Ref. 9; measurements taken at 295 K.
Percent difference between the value obtained in this work for molecular species 446 and that of Lacome et al. given in Ref. 9.
Table 4
Observed Pressure-Shift Constants d∘ for Self-Broadened N2O
|m|
Line
d∘
Zero Pressure Position
Band
Mol
1
P 1
−1.3
2321.7351
0400–0000
446
2
R 1
−0.8
1881.9325
1110(e)–0000
446
3
R 2
−0.6
1882.7612
1110(e)–0000
446
5
P 5
−0.2
1876.0448
1110(e)–0000
446
9
R 8
−0.6
1887.6683
1110(e)–0000
446
10
P10
−0.5
1871.7471
1110(e)–0000
446
11
P11
−1.6
2299.8989
0510(e)–0110(e)
446
11
P11
−1.3
2300.0336
0510(f)–0110(f)
446
11
P11
−1.2
2285.4478
0400–0000
448
12
P12
−1.3
2299.0754
0510(e)–0110(e)
446
12
P12
−1.3
2299.2389
0510(f)–0110(f)
446
12
P12
−0.8
2284.6830
0400–0000
448
13
P13
−1.7
2298.2532
0510(e)–0110(e)
446
13
P13
−1.4
2298.4483
0510(f)–0110(f)
446
13
P13
−1.6
2401.0708
1200–0000
448
14
R13
−1.5
1891.6715
1110(e)–0000
446
14
P14
−1.3
2297.6617
0510(f)–0110(f)
446
14
R13
−1.7
2334.6316
0400–0000
446
15
P15
−1.1
2399.4360
1200–0000
448
15
R14
−2.0
2321.7779
0510(e)–0110(e)
446
16
R15
−0.7
1893.2507
1110(e)–0000
446
16
P16
−1.4
2295.7942
0510(e)–0110(e)
446
16
P16
−1.7
2296.1004
0510(f)–0110(f)
446
17
R16
−1.9
1894.0356
1110(e)–0000
446
17
P17
−1.3
2295.3257
0510(f)–0110(f)
446
18
P18
−1.5
2294.5548
0510(f)–0110(f)
446
19
R18
−2.0
1895.5959
1110(e)–0000
446
19
P19
−2.0
2279.3909
0400–0000
448
19
P19
−0.3
2396.1424
1200–0000
448
20
R19
−1.8
1896.3713
1110(e)–0000
446
20
P20
−1.5
2293.0247
0510(f)–0110(f)
446
20
P20
−1.5
2278.6432
0400–0000
448
21
R20
−1.5
1897.1436
1110(e)–0000
446
21
P21
−1.1
2292.2653
0510(f)–0110(f)
446
22
R21
−1.8
1897.9126
1110(e)–0000
446
22
P22
−1.3
2291.5097
0510(f)–0110(f)
446
22
P22
−0.5
2393.6506
1200–0000
448
23
R22
−1.5
1898.6785
1110(e)–0000
446
23
P23
−1.2
2290.7577
0510(f)–0110(f)
446
24
R23
−1.9
1899.4412
1110(e)–0000
446
24
P24
−1.7
2391.9790
1200–0000
448
25
P25
−0.4
1858.3989
1110(e)–0000
446
25
R24
−1.3
1900.2007
1110(e)–0000
446
25
P25
−1.2
2391.1400
1200–0000
448
26
R25
−1.5
2345.3744
0400–0000
446
26
P26
−1.0
2390.2988
1200–0000
448
27
P27
−0.6
1856.5682
1110(e)–0000
446
27
P27
−1.4
2286.8647
0510(e)–0110(e)
446
27
P27
−0.9
2389.4555
1200–0000
448
28
P28
−0.4
1855.6483
1110(e)–0000
446
28
P28
−1.5
2300.2197
0400–0000
446
28
P28
−1.4
2286.0588
0510(e)–0110(e)
446
28
P28
−1.3
2287.0516
0510(f)–0110(f)
446
29
P29
−0.9
1854.7256
1110(e)–0000
446
29
R28
−1.7
1903.2069
1110(e)–0000
446
29
P29
−1.5
2299.4556
0400–0000
446
29
P29
−1.5
2285.2537
0510(e)–0110(e)
446
29
R28
−1.3
2335.1126
0510(f)–0110(f)
446
29
P29
−0.4
2387.7621
1200–0000
448
30
P30
−0.8
1853.7998
1110(e)–0000
446
30
R29
−1.8
1903.9505
1110(e)–0000
446
30
R29
−2.0
2349.0110
0400–0000
446
30
P30
−1.3
2284.4493
0510(e)–0110(e)
446
30
P30
−1.5
2285.5930
0510(f)–0110(f)
446
30
P30
−1.6
2386.9121
1200–0000
448
31
P31
−0.5
1852.8712
1110(e)–0000
446
31
R30
−1.9
1904.6908
1110(e)–0000
446
31
P31
−1.5
2297.9316
0400–0000
446
31
R30
−2.0
2349.9229
0400–0000
446
31
P31
−1.3
2284.8687
0510(f)–0110(f)
446
32
P32
−0.4
1851.9395
1110(e)–0000
446
32
R31
−2.1
1905.4280
1110(e)–0000
446
32
R31
−1.5
2350.8358
0400–0000
446
32
P32
−1.6
2284.1474
0510(f)–0110(f)
446
33
P33
−0.4
1851.0050
1110(e)–0000
446
33
R32
−2.6
1906.1619
1110(e)–0000
446
34
P34
−0.9
1850.0675
1110(e)–0000
446
35
P35
−1.0
1849.1270
1110(e)–0000
446
36
P36
−1.5
1848.1837
1110(e)–0000
446
37
P37
−1.1
1847.2374
1110(e)–0000
446
37
R36
−2.3
1909.0656
1110(e)–0000
446
37
R36
−1.8
2364.8366
0420(e)–0000
446
38
P38
−0.5
1846.2882
1110(e)–0000
446
38
P38
−1.5
2279.8820
0510(f)–0110(f)
446
38
R37
−1.7
2365.8331
0420(e)–0000
446
39
R38
−1.3
1910.4980
1110(e)–0000
446
39
P39
−1.8
2279.1806
0510(f)–0110(f)
446
40
P40
−1.3
2291.1239
0400–0000
446
40
R39
−1.3
2358.1566
0400–0000
446
40
P40
−2.3
2278.4818
0510(f)–0110(f)
446
41
P41
−1.9
1843.4233
1110(e)–0000
446
41
R40
−1.5
1911.9176
1110(e)–0000
446
41
P41
−1.2
2290.3705
0400–0000
446
41
P41
−1.7
2277.7853
0510(f)–0110(f)
446
42
P42
−0.6
1842.4626
1110(e)–0000
446
42
P42
−2.9
2123.3596
0111(e)–0110(e)
456
42
P42
−2.7
2123.2647
0111(f)–0110(f)
456
42
R41
−1.9
2345.1953
0510(e)–0110(e)
446
43
P43
−0.5
1841.4989
1110(e)–0000
446
43
R42
−1.7
1913.3243
1110(e)–0000
446
43
P43
−1.3
2288.8642
0400–0000
446
44
P44
−1.5
1840.5324
1110(e)–0000
446
44
P44
−1.3
2288.1112
0400–0000
446
44
R43
−1.5
2361.8180
0400–0000
446
45
P45
−1.3
2287.3582
0400–0000
446
45
P45
−0.4
1839.5631
1110(e)–0000
446
46
P46
−0.4
1838.5909
1110(e)–0000
446
46
P46
−1.5
2286.6051
0400–0000
446
46
R45
−1.4
2363.6462
0400–0000
446
47
P47
−0.5
1837.6158
1110(e)–0000
446
47
P47
−1.5
2285.8519
0400–0000
446
47
R46
−1.7
2364.5595
0400–0000
446
48
P48
−2.2
1836.6379
1110(e)–0000
446
48
P48
−1.3
2285.0984
0400–0000
446
50
P50
−3.0
2114.1826
0111(f)–0110(f)
456
50
R49
−1.9
2367.2949
0400–0000
446
51
R50
−1.5
2368.2052
0400–0000
446
53
P53
−2.6
2110.6717
0111(f)–0110(f)
456
54
P54
−2.4
2122.9995
0001–0000
456
55
R54
−0.8
2504.7519
1200–0000
446
56
P56
−1.8
2120.6119
0001–0000
456
57
P57
−2.1
2119.4085
0001–0000
456
58
P58
−1.7
2118.1987
0001–0000
456
61
P61
−1.8
2114.5310
0001–0000
456
63
P63
−1.8
2112.0541
0001–0000
456
65
P65
−1.1
2403.1525
1200–0000
446
66
P66
−0.5
2402.1553
1200–0000
446
67
P67
−1.4
2401.1546
1200–0000
446
73
R72
−4.2
2266.0319
0001–0000
446
74
R73
−2.5
2266.3487
0001–0000
446
75
R74
−3.0
2266.6584
0001–0000
446
76
R75
−3.0
2266.9608
0001–0000
446
77
R76
−2.4
2267.2561
0001–0000
446
79
R78
−2.5
2267.8252
0001–0000
446
81
R80
−2.8
2268.3655
0001–0000
446
82
R81
−3.3
2268.6248
0001–0000
446
Taken at 296 K; d∘ in cm−2 atm × 103; line positions in cm−1.
Table 5
Band Strengths Sv, Dipole-Moment Matrix Elements |R|, and F Factor Coefficients of N2Oa
Center in cm−1; Sv in cm−2/atm; |R| in debyes; measurements taken at 296 K. Values given within parentheses are estimated uncertainties in the last digit(s). ND denotes not determined.
The standard deviation difference in percent between the computed and measured line strengths for a band. An asterisk denotes a strongly perturbed line (not included in the least-squares analysis). A double asterisk denotes a strongly perturbed band. Analysis included perturbation treatment of interacting levels. F0 and Fxy are interaction parameters involved in the perturbation treatment of the line strengths. Value for Sv is the unperturbed vibrational band strength.
Table 6
Comparison of Studies on Measurements of N2O for the Determination of Band Strengths Sv and F Factor Coefficientsa
Observed-minus-calculated (O – C) strength difference, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 246 K.
Bands: 0200–0000 denoted with asterisk; 1000–0000 denoted with pound.
Table 8
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for Two π − π Bands 111 0(e)–0110(e) and 1110(f)–0110(f) of 14N216O
Observed-minus-calculated (O – C) strengths, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 1110(e)–0110(e) denoted with asterisk; 1110(f)–0110(f) denoted with pound.
Table 9
Computed Values of Line Positions, Line Strengths, Observed-minus-Calculateda Strengths, Results from Measurements of NO2 Samples at High Pressures,b Self-Broadened Half-Widths b∘, and Observed-minus-Smoothed, b∘ for the 1110–0000 and 2000–0110 Bands of 14N216O
Observed-minus-calculated (O – C) values, in percent.
50–504 Torr; positions in cm−1; strengths in cm−2/atm; b∘ in cm−1/atm; measurements taken at 296 K.
Observed-minus-smoothed (O – S) values, in percent. Smoothed values from this work given in Table 3 for 14N216O. Q-branch smoothed values derived from an average between |m| and |m| + 1 smoothed values with J = |m|.
Bands: 1110–0000 denoted with asterisk; 2000–0110 denoted with pound.
Table 10
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for the 0001–0000, 0111(e)–0110(e), and 0111(f)–0110(f) Bands of 14N216Ob
Observed-minus-calculated (O – C) values, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 0001–0000 denoted with asterisk; 0111(e)–0110(e) denoted with plus; 0111(f)–0110(f) denoted with minus.
Table 11
Computed Values of Line Positions, Line Strengths, Observed-minus-Calculateda Strengths, Results from Measurements of Samples at High Pressures,b Self-Broadened Half-Widths b∘, and Observed-minus-Smoothed b∘ for Three 14N216O Bandsc
High Pressure Results
Line
Position
Strength
O – C %
Strength
b∘ × 104
O – S %
*R 0
2323.41432
1.18E−03
2.5
1.20E−03
1240
−2.4
*R 1
2324.25876
2.35E−03
−2.6
2.45E−03
1200
−0.9
*R 2
2325.10639
3.50E−03
−1.2
*R 3
2325.95719
4.61E−03
−3.6
4.70E−03
1155
−0.2
*R 5
2327.66820
6.67E−03
−1.5
*R 6
2328.52835
7.59E−03
1.8
*R 7
2329.39153
8.43E−03
4.3
*R 8
2330.25770
9.18E−03
−1.2
*R 9
2331.12682
9.83E−03
−1.4
*R10
2331.99882
1.04E−02
−1.0
*R11
2332.87365
1.08E−02
0.0
1.08E−02
1035
−0.6
*R12
2333.75124
1.12E−02
3.4
*R13
2334.63153
1.14E−02
−1.8
1.14E−02
1015
−1.4
*R14
2335.51443
1.16E−02
−0.9
*R15
2336.39988
1.16E−02
−0.9
1.16E−02
1008
−0.1
*R16
2337.28778
1.15E−02
0.0
*R17
2338.17806
1.14E−02
0.0
1.15E−02
991
0.4
*R18
2339.07063
1.12E−02
−2.8
1.13E−02
978
−0.3
*R19
2339.96538
1.09E−02
−2.8
*R20
2340.86223
1.06E−02
−3.9
*R21
2341.76108
1.01E−02
−1.0
1.02E−02
970
0.5
*R23
2343.56434
9.21E−03
−2.3
9.33E−03
945
0.1
*R24
2344.46855
8.70E−03
−1.0
*R25
2345.37433
8.18E−03
−2.3
8.20E−03
937
−0.2
*R26
2346.28158
7.64E−03
3.0
*R27
2347.19016
7.10E−03
0.6
7.19E−03
915
−0.2
*R28
2348.09999
6.56E−03
−0.2
*R29
2349.01093
6.03E−03
0.0
6.20E−03
901
0.4
*R30
2349.92287
5.51E−03
6.6
5.62E−03
889
−0.5
*R31
2350.83570
5.02E−03
0.4
5.10E−03
867
−1.0
*R32
2351.74931
4.54E−03
1.3
*R33
2352.66356
4.09E−03
0.3
*R34
2353.57836
3.67E−03
0.8
3.80E−03
885
2.5
*R35
2354.49359
3.27E−03
−8.3
*R36
2355.40913
2.91E−03
2.0
3.04E−03
860
1.7
*R37
2356.32488
2.57E−03
1.9
2.64E−03
840
1.0
*R38
2357.24073
2.26E−03
2.2
*R39
2358.15657
1.98E−03
2.0
1.99E−03
818
−0.9
*R40
2359.07230
1.72E−03
1.7
*R43
2361.81793
1.11E−03
2.6
1.11E−03
785
−3.1
*R45
2363.64617
8.05E−04
3.6
8.25E−04
793
−1.3
*R46
2364.55941
6.82E−04
−1.2
6.85E−04
784
−1.1
*R48
2366.38382
4.83E−04
−1.9
4.83E−04
785
−0.9
*R49
2367.29489
4.04E−04
0.7
4.03E−04
765
−3.1
*R50
2368.20515
3.36E−04
−0.3
3.28E−04
767
−2.7
*R51
2369.11458
2.79E−04
−6.5
*R52
2370.02276
2.30E−04
0.0
2.24E−04
760
−2.1
*R53
2370.92999
1.89E−04
−1.1
*R54
2371.83624
1.55E−04
−3.3
1.53E−04
770
−1.4
*R55
2372.74122
1.26E−04
0.8
*R56
2373.64509
1.02E−04
−6.9
*R57
2374.54821
8.24E−05
−1.7
7.66E−05
760
−1.7
*R58
2375.44972
6.62E−05
−2.6
6.50E−05
780
0.5
*R59
2376.35011
5.30E−05
−3.1
*R60
2377.24925
4.22E−05
−3.2
*R61
2378.14703
3.35E−05
0.0
*R62
2379.04369
2.65E−05
−4.3
*R63
2379.93854
2.08E−05
−4.0
*R64
2380.83199
1.63E−05
−1.9
*R65
2381.72538
1.27E−05
−5.0
*R66
2382.61623
9.87E−06
−4.3
*P 1
2321.73506
1.18E−03
−2.6
1.19E−03
1270
0.0
*P 5
2318.41513
5.56E−03
0.0
*P 6
2317.59314
6.51E−03
−2.0
*P 7
2316.77431
7.38E03
−1.5
*P 8
2315.95862
8.16E−03
0.5
8.25E−03
1088
−1.0
*P10
2314.33650
9.44E−03
0.1
9.48E−03
1073
0.4
*P11
2313.53000
9.93E−03
−2.8
*P12
2312.72647
1.03E−02
−0.0
1.05E−02
1035
−0.6
*P13
2311.92587
1.06E−02
3.6
1.07E−02
1028
−1.1
*P15
2310.33320
1.09E−02
2.7
*P16
2309.54101
1.09E−02
0.0
1.10E−02
1010
0.1
*P17
2308.75150
1.08E−02
−2.9
1.09E−02
991
−0.2
*P18
2307.96458
1.06E−02
−3.9
1.07E−02
985
−0.2
*P19
2307.18019
1.04E−02
−2.0
1.04E−02
975
−0.6
*P20
2306.39824
1.01E−02
−1.0
1.01E−02
974
0.0
*P21
2305.61864
9.69E−03
−1.1
9.70E−03
966
0.1
*P23
2304.06616
8.83E−03
−2.1
*P24
2303.29309
8.36E−03
−0.1
*P25
2302.52201
7.87E−03
−1.8
7.96E−03
951
0.8
*P26
2301.75282
7.36E−03
−0.6
7.55E−03
943
0.4
*P27
2300.98541
6.85E−03
−1.6
6.95E−03
933
1.1
*P28
2300.21969
6.34E−03
−0.2
6.40E−03
915
−0.2
*P29
2299.45555
5.83E−03
−0.5
5.84E−03
900
−1.0
*P30
2298.69289
5.34E−03
0.0
*P31
2297.93159
4.86E−03
−1.3
4.90E−03
890
−0.3
*P32
2297.17156
4.41E−03
−0.2
4.42E−03
870
−0.7
*P33
2296.41267
3.97E−03
3.4
*P34
2295.65484
3.57E−03
−0.9
*P35
2294.89794
3.18E−03
2.2
*P36
2294.14187
2.83E−03
0.7
*P37
2293.38654
2.50E−03
2.7
*P38
2292.63182
2.20E−03
1.3
*P39
2291.87763
1.93E−03
0.0
1.94E−03
827
−0.4
*P40
2291.12387
1.68E−03
−3.7
1.68E−03
815
−1.2
*P41
2290.37043
1.46E−03
0.0
1.46E−03
815
−1.0
*P42
2289.61723
1.26E−03
−1.6
1.27E−03
810
−1.2
*P43
2288.86418
1.08E−03
2.7
1.09E−03
805
−1.6
*P44
2288.11119
9.26E−04
5.5
9.33E−04
799
−1.3
*P45
2287.35819
7.88E−04
1.5
7.91E−04
797
−1.3
*P46
2286.60510
6.69E−04
−0.6
6.70E−04
797
−0.8
*P47
2285.85185
5.64E−04
−0.2
5.67E−04
789
−0.5
*P48
2285.09839
4.74E−04
2.9
4.72E−04
788
−0.4
*P50
2283.59061
3.30E−04
2.4
*P51
2282.83621
2.74E−04
−7.5
*P53
2281.32626
1.86E−04
−1.1
*P54
2280.57027
1.52E−04
6.7
*P55
2279.81379
1.24E−04
−7.8
*P56
2279.05679
1.00E−04
−3.1
*P57
2278.29899
8.11E−05
4.6
*P58
2277.54055
6.52E−05
−1.9
*P59
2276.78187
5.22E−05
−2.8
*P60
2276.02205
4.16E−05
−2.7
*P64
2272.97587
1.61E−05
−5.2
+R 1
2310.72642
2.11E−04
1.9
+R 4
2313.25774
6.51E−04
2.8
+R 5
2314.10416
7.75E−04
−1.0
7.70E−04
1125
−0.1
+R 7
2315.80089
9.93E−04
−1.0
+R 9
2317.50266
1.16E−03
3.3
+R13
2320.92059
1.36E−03
−0.7
+R14
2321.77791
1.38E−03
4.8
1.37E−03
1018
−0.2
+R15
2322.63630
1.38E−03
2.8
+R16
2323.49573
1.38E−03
4.2
1.37E−03
990
−0.3
+R17
2324.35616
1.36E−03
−1.5
1.36E−03
991
0.4
+R18
2325.21755
1.34E−03
0.0
+R19
2326.07988
1.30E−03
0.0
1.32E−03
990
1.6
+R20
2326.94309
1.26E−03
3.1
+R21
2327.80715
1.21E−03
−0.8
+R23
2329.53764
1.10E−03
−1.9
+R25
2331.27104
9.81E−04
−2.1
+R26
2332.13865
9.16E−04
−2.3
+R27
2333.00688
8.52E−04
5.3
8.52E−04
900
−1.9
+R28
2333.87564
7.88E−04
−3.7
+R29
2334.74488
7.25E−04
2.0
+R30
2335.61455
6.63E−04
−0.5
+R32
2337.35501
5.47E−04
−0.9
+R33
2338.22569
4.93E−04
0.0
+R34
2339.09660
4.42E−04
−0.9
+R36
2340.83893
3.51E−04
−2.0
+R37
2341.71025
3.10E−04
−1.6
+R38
2342.58160
2.73E−04
1.1
+R39
2343.45293
2.39E−04
0.4
2.41E−04
840
1.8
+R40
2344.32419
2.08E−04
−1.5
+R41
2345.19534
1.81E−04
−1.6
1.81E−04
820
0.0
+R42
2346.06633
1.56E−04
3.1
+R44
2347.80762
1.15E−04
−3.6
+R46
2349.54769
8.31E−05
−2.6
+R47
2350.41715
7.01E−05
−3.3
+R48
2351.28618
5.90E−05
−1.0
+R49
2352.15404
4.93E−05
4.8
+R50
2353.02213
4.11E−05
0.0
+R51
2353.88928
3.41E−05
−3.0
+R52
2354.75585
2.82E−05
0.0
+R53
2355.62172
2.35E−05
−2.6
+R54
2356.48646
1.90E−05
−1.6
+R59
2360.79887
6.54E−06
1.7
+P 2
2307.37028
2.10E−04
0.9
+P 3
2306.53467
3.68E−04
−0.8
+P 4
2305.70043
5.09E−04
−0.4
+P 5
2304.86756
6.39E−04
0.2
+P 6
2304.03607
7.58E−04
−2.4
+P 7
2303.20594
8.66E−04
−1.5
+P 8
2302.37716
9.63E−04
−0.3
9.57E−04
1100
0.1
+P 9
2301.54973
1.05E−03
−1.0
1.03E−03
1065
−1.4
+P10
2300.72363
1.12E−03
−2.8
1.12E−03
1071
0.2
+P11
2299.89885
1.18E−03
1.7
1.18E−03
1055
0.5
+P12
2299.07539
1.23E−03
0.8
1.24E−03
1032
−0.9
+P13
2298.25321
1.27E−03
−0.8
1.30E−03
1028
−1.1
+P14
2297.43230
1.29E−03
−1.6
1.30E−03
1025
−0.4
+P15
2296.61264
1.30E−03
1.5
1.31E−03
1021
0.1
+P16
2295.79421
1.30E−03
0.0
1.30E−03
1001
−0.8
+P17
2294.97698
1.29E−03
−4.9
+P18
2294.16094
1.27E−03
0.0
+P19
2293.34604
1.24E−03
0.8
+P20
2292.53227
1.21E−03
5.5
+P21
2291.71960
1.17E−03
2.5
1.17E−03
968
0.3
+P22
2290.90799
1.12E−03
−1.8
1.12E−03
966
0.5
+P23
2290.09741
1.06E−03
1.9
+P24
2289.28783
1.01E−03
−3.0
+P25
2288.47921
9.50E−04
2.7
+P26
2287.67153
8.89E−04
−1.4
+P27
2286.86473
8.28E−04
−0.2
8.32E−04
926
0.3
+P28
2286.05878
7.67E−04
−3.9
7.62E−04
915
−0.2
+P29
2285.25366
7.06E−04
−1.6
7.06E−04
911
0.2
+P30
2284.44930
6.47E−04
−0.8
6.44E−04
899
0.2
+P31
2283.64569
5.90E−04
−1.2
+P32
2282.84276
5.35E−04
2.6
+P33
2282.04050
4.83E−04
1.4
+P34
2281.23884
4.34E−04
−3.1
+P35
2280.43776
3.88E−04
−3.5
+P36
2279.63721
3.45E−04
−1.2
+P37
2278.83715
3.05E−04
3.8
+P38
2278.03753
2.69E−04
0.4
+P39
2277.23832
2.36E−04
0.4
+P40
2276.43947
2.06E−04
−5.1
+P41
2275.64094
1.79E−04
−2.3
+P42
2274.84269
1.54E−04
−1.3
+P44
2273.24687
1.14E−04
−0.9
+P45
2272.44923
9.70E−05
−1.3
+P46
2271.65170
8.24E−05
0.8
+P47
2270.85426
6.96E−05
−0.7
+P48
2270.05687
5.85E−05
−0.2
+P49
2269.25950
4.90E−05
2.8
+P50
2268.46210
4.09E−05
3.1
+P51
2267.66425
3.39E−05
−0.6
+P52
2266.86646
2.80E−05
−2.6
+P53
2266.06849
2.31E−05
3.8
+P54
2265.27038
1.89E−05
−0.5
−R 1
2310.73783
2.14E−04
−0.9
−R 2
2311.59016
3.77E−04
3.1
−R 3
2312.44660
5.24E−04
3.9
−R 4
2313.30713
6.60E−04
−2.0
−R 5
2314.17174
7.86E−04
−4.5
7.87E−04
1130
0.4
−R 6
2315.04042
9.02E−04
−1.8
−R 7
2315.91314
1.01E−03
−3.8
9.78E−04
1095
−0.4
−R 8
2316.78988
1.10E−03
3.5
−R 9
2317.67062
1.18E−03
4.8
−R10
2318.55532
1.25E−03
0.0
−R11
2319.44396
1.30E−03
−1.6
−R12
2320.33650
1.35E−03
0.7
1.34E−03
1035
−0.4
−R14
2322.13317
1.39E−03
−1.5
1.39E−03
1010
−1.0
−R16
2323.94502
1.39E−03
−1.5
1.39E−03
998
0.5
−R18
2325.77169
1.35E−03
−3.1
1.35E−03
985
0.4
−R19
2326.69047
1.32E−03
−3.1
−R20
2327.61281
1.28E−03
−0.8
−R21
2328.53866
1.23E−03
1.6
−R22
2329.46796
1.17E−03
1.7
−R24
2331.33665
1.05E−03
−1.0
−R25
2332.27593
9.90E−04
2.0
−R26
2333.21839
9.25E−04
−1.6
9.26E−04
923
0.0
−R21
2334.16398
8.60E−04
−4.4
−R28
2335.11262
7.95E−04
4.2
8.23E−04
905
−0.4
−R30
2337.01874
6.68E−04
1.6
6.80E−04
893
0.0
−R31
2337.97606
6.08E−04
−2.5
6.27E−04
883
0.8
−R32
2338.93610
5.51E−04
1.6
−R33
2339.89879
4.96E−04
−3.1
−R35
2341.83171
3.97E−04
−1.0
−R36
2342.80176
3.52E−04
8.3
−R31
2343.77406
3.11E−04
−2.3
3.15E−04
831
−0.1
−R38
2344.74852
2.74E−04
−0.4
2.70E−04
815
−1.8
−R39
2345.72503
2.39E−04
0.4
−R40
2346.70348
2.09E−04
3.2
2.11E−04
820
−0.4
−R44
2350.63436
1.15E−04
0.9
−R45
2351.62075
9.76E−05
7.0
−R49
2355.57713
4.90E−05
1.4
−R50
2356.56870
4.08E−05
−2.3
−R51
2357.56048
3.38E−05
4.0
−R52
2358.55277
2.79E−05
1.4
−R57
2363.51594
9.99E−06
−5.0
−R58
2364.50744
8.03E−06
−3.5
−R59
2365.49837
6.42E−06
0.3
−R60
2366.48819
5.12E−06
1.9
−P 2
2307.36981
2.12E−04
−2.4
−P 3
2306.53816
3.73E−04
−1.4
−P 4
2305.71065
5.15E−04
0.8
−P 5
2304.88727
6.46E−04
0.0
−P 7
2303.25293
8.76E−04
−1.9
−P 8
2302.44194
9.73E−04
−3.5
9.63E−04
1105
0.5
−P 9
2301.63506
1.06E−03
8.6
1.06E−03
1077
−0.3
−P10
2300.83227
1.13E−03
−2.7
1.13E−03
1081
1.1
−P11
2300.03356
1.19E−03
−1.7
1.18E−03
1055
0.5
−P12
2299.23890
1.24E−03
3.1
1.24E−03
1034
−0.7
−P13
2298.44828
1.28E−03
0.0
1.27E−03
1025
−1.4
−P14
2297.66168
1.30E−03
−1.6
1.30E−03
1027
−0.2
−P15
2296.87906
1.31E−03
1.5
−P16
2296.10040
1.31E−03
1.5
1.31E−03
1005
−0.4
−P17
2295.32567
1.30E−03
−0.8
1.30E−03
995
0.2
−P18
2294.55483
1.28E−03
0.8
1.27E−03
983
−0.4
−P19
2293.78786
1.25E−03
−0.8
−P20
2293.02470
1.21E−03
0.0
1.23E−03
975
0.1
−P21
2292.26533
1.17E−03
0.9
1.17E−03
963
−0.2
−P22
2291.50969
1.12E−03
0.9
1.12E−03
955
−0.6
−P23
2290.75774
1.07E−03
1.8
1.07E−03
957
0.3
−P24
2290.00943
1.01E−03
1.0
1.01E−03
940
−0.4
−P27
2287.78585
8.27E−04
−2.1
−P28
2287.05157
7.65E−04
−0.7
7.65E−04
916
−0.1
−P29
2286.32066
7.04E−04
0.9
7.10E−04
901
−0.9
−P30
2285.59304
6.45E−04
−4.4
6.42E−04
890
−0.8
−P31
2284.86865
5.87E−04
−0.3
5.87E−04
886
−0.8
−P32
2284.14741
5.32E−04
3.4
5.35E−04
877
0.1
−P33
2283.42926
4.80E−04
−1.5
4.81E−04
855
−1.2
−P34
2282.71412
4.31E−04
−0.9
−P35
2282.00190
3.84E−04
−1.1
−P36
2281.29253
3.42E−04
−0.6
−P37
2280.58592
3.02E−04
−2.0
−P38
2279.88198
2.66E−04
5.3
2.69E−04
825
−0.9
−P39
2279.18062
2.33E−04
3.7
2.37E−04
835
0.6
−P40
2278.48175
2.03E−04
3.8
2.02E−04
825
0.0
−P41
2277.78527
1.76E−04
2.8
1.76E−04
828
0.6
−P42
2277.09108
1.52E−04
5.6
−P44
2275.70913
1.12E−04
−1.8
−P46
2274.33505
8.06E−05
−2.9
−P47
2273.65068
6.81E−05
0.9
−P48
2272.96792
5.72E−05
5.1
−P49
2272.28665
4.78E−05
−2.8
−P51
2270.92808
3.30E−05
−1.5
−P52
2270.25097
2.72E−05
−2.2
−P57
2266.87704
9.77E−06
−5.5
50–504 Torr; positions in cm−1; strengths in cm−2/atm; b∘ in cm−1/atm; measurements taken at 296 K.
Observed-minus-smoothed (O – S) values, in percent; smoothed values for 14N216O given in Table 3.
Bands: 0400–0000 denoted with asterisk; 0510(e)–0110(e) denoted with plus; 0510(f)–0110(f) denoted with minus.
Table 12
Computed Values of Line Positions, Line Strengths and Observed-minus-Calculateda Strengths, for the 1200–0000, 1310(e)–0110(e), and 1310(f)–0110(f) Bands of 14N216Ob
Observed-minus-calculated (O – C) values, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 1200–0000 denoted with asterisk; 1310(e)–0110(e) denoted with plus; 1310(f)–0110(f) denoted with minus.
Table 13
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for Bands of 14N216Ob 2000–0000, 2110(e)–0110(e), and 2110(f)–0110(f)
Line
Position
Strength
O– C%
*R 0
2564.17065
6.11E−02
1.8
*R 1
2564.99505
1.22E−01
0.0
*R 2
2565.81262
1.81E−01
−0.6
*R 3
2566.62338
2.39E−01
1.8
*R 4
2567.42731
2.94E−01
0.5
*R 5
2568.22441
3.46E−01
0.5
*R 6
2569.01468
3.94E−01
1.2
*R 7
2569.79812
4.37E−01
0.0
*R 8
2570.57473
4.76E−01
0.9
*R 9
2571.34450
5.10E−01
0.2
*R10
2572.10744
5.39E−01
1.0
*R11
2572.86353
5.62E−01
2.1
*R12
2573.61279
5.80E−01
0.0
*R13
2574.35521
5.93E−01
0.9
*R14
2575.09079
6.00E−01
−0.5
*R15
2575.81954
6.03E−01
0.5
*R16
2576.54144
6.00E−01
2.2
*R17
2577.25651
5.93E−01
1.7
*R18
2577.96475
5.82E−01
0.5
*R19
2578.66616
5.67E−01
−0.3
*R20
2579.36073
5.49E−01
1.2
*R21
2580.04848
5.28E−01
0.8
*R22
2580.72940
5.05E−01
1.1
*R23
2581.40350
4.80E−01
−0.5
*R24
2582.07079
4.54E−01
0.0
*R25
2582.73126
4.26E−01
0.3
*R26
2583.38492
3.98E−01
0.8
*R27
2584.03178
3.70E−01
0.6
*R28
2584.67185
3.42E−01
0.7
*R29
2585.30512
3.15E−01
1.5
*R30
2585.93161
2.88E−01
−0.5
*R31
2586.55132
2.62E−01
0.9
*R32
2587.16426
2.37E−01
0.5
*R33
2587.77044
2.14E−01
0.7
*R34
2588.36987
1.92E−01
0.0
*R35
2588.96255
1.71E−01
0.0
*R36
2589.54850
1.52E−01
0.9
*R37
2590.12773
1.34E−01
0.0
*R38
2590.70024
1.18E−01
1.0
*R39
2591.26606
1.03E−01
1.8
*R40
2591.82519
8.99E−02
0.7
*R41
2592.37764
7.80E−02
0.7
*R42
2592.92343
6.73E−02
1.1
*R43
2593.46258
5.79E−02
0.0
*R44
2593.99509
4.95E−02
2.7
*R45
2594.52100
4.21E−02
−0.5
*R46
2595.04030
3.57E−02
0.3
*R47
2595.55302
3.01E−02
−1.0
*R48
2596.05918
2.53E−02
0.8
*R49
2596.55880
2.12E−02
0.7
*R50
2597.05190
1.76E−02
−2.4
*R51
2597.53850
1.46E−02
0.7
*R52
2598.01862
1.21E−02
−0.4
*R54
2598.95952
8.10E−03
0.8
*R56
2599.87480
5.35E−03
−0.7
*R57
2600.32290
4.32E−03
0.3
*R58
2600.76468
3.47E−03
−1.2
*R59
2601.20017
2.78E−03
1.5
*R60
2601.62939
2.22E−03
1.2
*R61
2602.05239
1.76E−03
−3.9
*R62
2602.46919
1.39E−03
−1.3
*R63
2602.87983
1.09E−03
−1.1
*R64
2603.28435
8.56E−04
0.2
*R65
2603.68278
6.68E−04
−0.9
*R66
2604.07517
5.19E−04
0.0
*R67
2604.46156
4.01E−04
−0.7
*R68
2604.84198
3.09E−04
−4.6
*R69
2605.21649
2.37E−04
2.2
*R70
2605.58513
1.81E−04
−3.9
*R71
2605.94794
1.38E−04
−1.1
*R73
2606.65630
7.85E−05
−2.5
*R74
2607.00195
5.90E−05
0.0
*R76
2607.67647
3.28E−05
4.1
*R77
2608.00595
2.44E−05
−5.8
*R81
2609.26769
7.06E−06
−1.7
*R83
2609.86754
3.71E−06
0.9
*R84
2610.15990
2.67E−06
−2.6
*P 1
2562.50142
6.08E−02
−0.5
*P 2
2561.65659
1.21E−01
0.0
*P 3
2560.80496
1.79E−01
0.0
*P 4
2559.94653
2.34E−01
1.2
*P 5
2559.08131
2.87E−01
1.8
*P 6
2558.20931
3.36E−01
−0.5
*P 7
2557.33052
3.81E−01
2.7
*P 8
2556.44496
4.21E−01
−0.2
*P 9
2555.55262
4.56E−01
1.5
*P10
2554.65353
4.87E−01
1.8
*P11
2553.74768
5.12E−01
2.0
*P12
2552.83508
5.31E−01
0.9
*P13
2551.91575
5.46E−01
1.7
*P14
2550.98968
5.55E−01
0.0
*P15
2550.05688
5.59E−01
1.6
*P16
2549.11737
5.59E−01
0.8
*P17
2548.17116
5.54E−01
3.1
*P18
2547.21824
5.45E−01
0.7
*P19
2546.25864
5.32E−01
2.3
*P20
2545.29236
5.16E−01
1.2
*P21
2544.31941
4.97E−01
−0.8
*P22
2543.33981
4.76E−01
0.9
*P23
2542.35356
4.53E−01
−0.1
*P24
2541.36067
4.29E−01
0.4
*P25
2540.36117
4.03E−01
0.8
*P26
2539.35505
3.77E−01
−0.4
*P27
2538.34234
3.51E−01
−0.9
*P28
2537.32304
3.24E−01
−0.6
*P29
2536.29717
2.98E−01
0.7
*P30
2535.26475
2.73E−01
0.5
*P31
2534.22578
2.49E−01
1.9
*P32
2533.18029
2.25E−01
−0.9
*P33
2532.12829
2.03E−01
−0.9
*P34
2531.06979
1.82E−01
0.0
*P35
2530.00481
1.62E−01
−0.8
*P36
2528.93338
1.44E−01
0.0
*P37
2527.85550
1.27E−01
0.5
*P38
2526.77119
1.12E−01
1.8
*P39
2525.68048
9.81E−02
0.8
*P40
2524.58338
8.55E−02
−0.1
*P41
2523.47992
7.41E−02
0.6
*P42
2522.37011
6.40E−02
0.4
*P43
2521.25398
5.50E−02
−1.0
*P44
2520.13155
4.70E−02
0.5
*P45
2519.00284
4.00E−02
−0.2
*P46
2517.86788
3.39E−02
1.8
*P47
2516.72668
2.86E−02
1.8
*P48
2515.57928
2.40E−02
−0.9
*P49
2514.42571
2.01E−02
0.1
*P50
2513.26598
1.67E−02
−0.7
*P51
2512.10013
1.39E−02
−0.3
*P52
2510.92818
1.14E−02
1.5
*P53
2509.75017
9.39E−03
−1.1
*P54
2508.56613
7.68E−03
−0.3
*P55
2507.37608
6.25E−03
−0.7
*P56
2506.18007
5.07E−03
−0.5
*P57
2504.97812
4.09E−03
−0.4
*P58
2503.77027
3.29E−03
−0.4
*P59
2502.55656
2.63E−03
0.0
*P60
2501.33702
2.10E−03
−1.6
*P62
2498.88061
1.31E−03
−1.6
*P63
2497.64382
1.03E−03
0.9
*P64
2496.40137
8.08E−04
−2.2
*P65
2495.15330
6.30E−04
−3.2
*P66
2493.89965
4.89E−04
0.2
*P67
2492.64047
3.78E−04
−5.6
*P68
2491.37581
2.91E−04
−2.8
*P70
2488.83024
1.70E−04
−1.3
*P71
2487.54943
1.30E−04
−1.9
*P72
2486.26336
9.80E−05
−1.2
*P73
2484.97206
7.39E−05
−1.2
*P74
2483.67561
5.54E−05
6.1
*P75
2482.37406
4.14E−05
−7.5
*P76
2481.06747
3.08E−05
−4.5
*P77
2479.75591
2.29E−05
−6.2
*P78
2478.43944
1.69E−05
−2.2
*P79
2477.11813
1.24E−05
−1.5
*P80
2475.79205
9.07E−06
−0.7
*P81
2474.46127
6.61E−06
−3.8
*P82
2473.12588
4.80E−06
−7.8
*P83
2471.78593
3.47E−06
−2.0
+R 1
2578.74246
4.60E−03
0.0
+R 2
2579.56081
8.11E−03
1.3
+R 3
2580.37248
1.13E−02
2.9
+R 4
2581.17748
1.42E−02
1.4
+R 5
2581.97579
1.69E−02
2.3
+R 6
2582.76742
1.94E−02
0.5
+R 7
2583.55236
2.17E−02
2.4
+R 8
2584.33061
2.37E−02
0.5
+R 9
2585.10216
2.54E−02
1.5
+R10
2585.86703
2.69E−02
1.4
+R11
2586.62520
2.81E−02
0.7
+R12
2587.37667
2.90E−02
−0.8
+R13
2588.12145
2.97E−02
4.2
+R14
2588.85953
3.01E−02
2.7
+R15
2589.59091
3.02E−02
3.2
+R16
2590.31559
3.01E−02
1.3
+R17
2591.03358
2.98E−02
3.1
+R18
2591.74487
2.92E−02
1.4
+R19
2592.44946
2.85E−02
2.2
+R20
2593.14736
2.76E−02
2.3
+R21
2593.83856
2.65E−02
2.5
+R23
2595.20089
2.41E−02
2.8
+R24
2595.87202
2.28E−02
1.8
+R25
2596.53647
2.14E−02
0.9
+R26
2597.19423
2.00E−02
1.0
+R27
2597.84532
1.86E−02
−0.5
+R29
2599.12746
1.58E−02
1.9
+R30
2599.75853
1.45E−02
1.7
+R31
2600.38294
1.32E−02
1.1
+R32
2601.00069
1.19E−02
0.0
+R33
2601.61178
1.07E−02
1.5
+R34
2602.21623
9.62E−03
0.3
+R35
2602.81404
8.59E−03
1.1
+R36
2603.40521
7.62E−03
0.3
+R37
2603.98976
6.74E−03
−0.3
+R38
2604.56768
5.93E−03
0.6
+R39
2605.13900
5.19E−03
0.4
+R40
2605.70371
4.52E−03
2.2
+R41
2606.26182
3.92E−03
0.0
+R42
2606.81335
3.38E−03
0.0
+R43
2607.35830
2.91E−03
−4.9
+R44
2607.89669
2.49E−03
1.0
+R45
2608.42852
2.12E−03
0.0
+R46
2608.95381
1.79E−03
−1.9
+R47
2609.47257
1.51E−03
0.4
+R49
2610.49053
1.06E−03
−2.2
+R50
2610.98977
8.85E−04
0.6
+R51
2611.48253
7.34E−04
−1.2
+R52
2611.96883
6.05E−04
−2.1
+R53
2612.44868
4.97E−04
−0.5
+R54
2612.92209
4.07E−04
−3.0
+R55
2613.38910
3.31E−04
−1.6
+R56
2613.84970
2.69E−04
−0.6
+R57
2614.30394
2.17E−04
−1.3
+R58
2614.75181
1.74E−04
−1.3
+R59
2615.19335
1.40E−04
1.8
+R60
2615.62857
1.11E−04
1.6
+R61
2616.05750
8.82E−05
−6.1
+R63
2616.89658
5.48E−05
0.0
+R64
2617.30678
4.29E−05
−2.2
+R65
2617.71079
3.35E−05
−5.3
+R66
2618.10863
2.60E−05
−11.1
+R67
2618.50033
2.01E−05
−2.1
+R68
2618.88593
1.55E−05
−0.6
+R69
2619.26546
1.19E−05
−1.5
+R70
2619.63895
9.07E−06
−1.9
+P 2
2575.40238
4.55E−03
−1.2
+P 3
2574.55071
8.00E−03
2.0
+P 4
2573.69239
1.11E−02
−0.5
+P 6
2571.95581
1.64E−02
5.5
+P 8
2570.19269
2.09E−02
−3.3
+P 9
2569.30119
2.27E−02
4.7
+P10
2568.40308
2.43E−02
2.2
+P11
2567.49835
2.55E−02
2.1
+P12
2566.58702
2.66E−02
2.0
+P13
2565.66910
2.73E−02
0.7
+P14
2564.74459
2.78E−02
0.0
+P15
2563.81349
2.80E−02
1.7
+P16
2562.87582
2.80E−02
1.7
+P17
2561.93159
2.78E−02
1.5
+P18
2560.98080
2.73E−02
3.5
+P19
2560.02346
2.67E−02
0.4
Observed-minus-calculated (O – C) values, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 2000–0000 denoted with asterisk; 2110–0110(e) denoted with plus; 2110(f)–0110(f) denoted with minus.
Table 14
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for the Four Δ–∑ Bandsb of 14N216O at 296 K
Observed-minus-calculated (O – C) values, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 0220(e)–0000 denoted with asterisk; 0420(e)–0000 denoted with pound; 1220(e)–0000 denoted with plus; 0221(e)–0000 denoted with minus.
Table 15
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for the 1001–0000, 1111(e)–0110(e), and 1111(f)–0110(f) Bands of 14N216O†
Line
Position
Strength
O – C %
*R 0
3481.64677
8.31E−02
2.6
*R 2
3483.27054
2.46E−01
2.2
*R 3
3484.06674
3.25E−01
1.6
*R 4
3484.85247
3.99E−01
0.9
*R 5
3485.62773
4.70E−01
0.2
*R 6
3486.39251
5.35E−01
0.3
*R 7
3487.14682
5.95E−01
0.0
*R 9
3488.62398
6.94E−01
−0.6
*R10
3489.34684
7.33E−01
−1.2
*R11
3490.05920
7.65E−01
−0.6
*R12
3490.76107
7.90E−01
−1.2
*R13
3491.45244
8.07E−01
−1.0
*R14
3492.13331
8.17E−01
−0.7
*R15
3492.80368
8.21E−01
−0.7
*R16
3493.46354
8.17E−01
−1.4
*R17
3494.11290
8.08E−01
−1.5
*R19
3495.38008
7.73E−01
−1.5
*R20
3495.99790
7.49E−01
−0.6
*R21
3496.60520
7.20E−01
0.2
*R23
3497.78824
6.55E−01
−0.3
*R24
3498.36398
6.19E−01
0.0
*R25a
3498.92920
5.82E−01
−0.2
*R26a
3499.48407
5.44E−01
−0.4
*R27a
3500.02970
5.06E−01
−2.4
*R28a
3500.56140
4.68E−01
0.0
*R29a
3501.08471
4.30E−01
0.6
*R30
3501.59739
3.94E−01
−0.2
*R31
3502.09944
3.59E−01
0.4
*R32
3502.59096
3.25E−01
0.4
*R33
3503.07195
2.93E−01
0.4
*R34a
3503.54264
2.63E−01
1.2
*R35a
3504.00263
2.35E−01
0.2
*R36a
3504.45214
2.08E−01
1.3
*R37a
3504.89111
1.84E−01
0.4
*R38a
3505.31960
1.62E−01
0.6
*R39a
3505.73757
1.42E−01
0.7
*R40a
3506.14522
1.24E−01
1.0
*R41a
3506.54229
1.07E−01
0.6
*R42a
3506.92912
9.28E−02
1.0
*R43a
3507.30600
7.97E−02
−0.3
*R44a
3507.67523
6.83E−02
0.5
*R45a
3507.99683
5.82E−02
−20.6
*R46a
3508.36177
4.93E−02
−0.2
*R47a
3508.69787
4.16E−02
0.4
*R48a
3509.02180
3.50E−02
0.8
*R49a
3509.33502
2.93E−02
−0.3
*R50a
3509.63747
2.44E−02
1.2
*R51a
3509.92930
2.02E−02
0.8
*R52a
3510.21068
1.67E−02
1.7
*R53a
3510.48142
1.37E−02
1.8
*R54a
3510.74181
1.13E−02
1.3
*R55a
3510.99163
9.17E−03
1.6
*R56a
3511.23095
7.44E−03
0.8
*R57a
3511.45974
6.01E−03
0.1
*R58
3511.67822
4.84E−03
0.0
*R59
3511.88609
3.88E−03
0.4
*R61
3512.27051
2.46E−03
0.2
*R62
3512.44707
1.94E−03
−0.1
*R63
3512.61321
1.53E−03
2.0
*R64
3512.76894
1.20E−03
−0.7
*R65
3512.91427
9.36E−04
0.6
*R66
3513.04921
7.28E−04
−0.1
*R67
3513.17377
5.63E−04
0.0
*R68
3513.28795
4.34E−04
0.6
*R69
3513.39178
3.33E−04
1.1
*R70
3513.48526
2.55E−04
1.6
*R71
3513.56840
1.94E−04
4.9
*R72
3513.64122
1.47E−04
−2.8
*R73
3513.70373
1.11E−04
−3.7
*R74
3513.75594
8.34E−05
−4.2
*R75
3513.79787
6.24E−05
1.4
*R76
3513.82954
4.65E−05
−2.0
*R77
3513.85096
3.45E−05
−1.0
*R82
3513.80486
7.31E−06
−7.6
*R84
3513.71528
3.82E−06
8.2
*P 1
3479.98118
8.27E−02
1.3
*P 2
3479.13271
1.64E−01
1.8
*P 3
3478.27380
2.43E−01
1.2
*P 4
3477.40445
3.19E−01
1.1
*P 5
3476.52467
3.90E−01
1.7
*P 6
3475.63447
4.57E−01
0.9
*P 7
3474.73383
5.18E−01
2.9
*P 8
3473.82278
5.73E−01
0.3
*P 9
3472.90132
6.21E−01
−0.1
*P10
3471.96944
6.62E−01
−0.3
*P11
3471.02716
6.96E−01
−0.5
*P12
3470.07448
7.23E−01
−1.4
*P13
3469.11141
7.43E−01
−0.1
*P14
3468.13795
7.55E−01
−1.4
*P15
3467.15411
7.61E−01
1.5
*P16
3466.15989
7.61E−01
−0.8
*P17
3465.15530
7.54E−01
−1.1
*P18
3464.14034
7.42E−01
−0.7
*P19
3463.11502
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−P59a
3406.57420
2.00E−04
−66.7
−P60a
3405.24018
1.59E−04
−6.0
−P61a
3403.82057
1.26E−04
1.5
−P62a
3402.38635
9.96E−05
3.3
−P63a
3400.94111
7.83E−05
−5.0
−P64a
3399.48600
6.12E−05
−2.1
−P65a
3398.02140
4.77E−05
3.6
−P66a
3396.54740
3.70E−05
11.0
−P67a
3395.06392
2.86E−05
4.6
−P69
3392.06890
1.69E−05
−5.4
−P74
3384.42392
4.18E−06
−1.7
Computed line strengths were calculated from constants given in Table 5 (unperturbed) whereas the computed (unperturbed) line positions were derived from constants given in Ref. 4 and corrected to the “true” values for the perturbed transitions. Line positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Perturbed transitions.
Table 16
Observed Line Positions, Line Strengths, Percent Observed, Observed-minus-Calculated Strengths, and Computed Strengthsa of Perturbed Transitions in Bands and Lines of 14N216O and 15N14N16Ob
Line Strength
Mol
Band
Line
Position
Observed
% Obs
Computed
O – C%
446
0710(f)–0110(f)
R56
3503.6643
7.00E−06
10
7.22E−06
−3.1
446
0710(f)–0110(f)
P58
3407.3443
6.18E−06
15
4.44E−06
28.2
446
0710(f)–0110(f)
R57
3504.8095
1.43E−04
4
1.44E−04
−0.7
446
0710(f)–0110(f)
P59
3406.8242
8.99E−05
8
8.79E−05
2.2
446
0730(f)–0110(f)
R36
3497.04547
1.68E−04
3
1.84E−04
−9.5
446
0730(f)–0110(f)
P38
3434.1260
1.49E−04
10
1.36E−04
8.7
446
0730(f)–0110(f)
R37
3498.0315
3.06E−05
4
2.99E−05
2.3
446
0730(f)–0110(f)
P39
3433.436
1.88E−05
10
2.22E−05
−18.1
446
0730(e)–0110(e)
R34
3495.992
4.01E−04
10
4.01E−04
0.0
446
0730(e)–0110(e)
P36
3436.533
3.24E−04
10
3.05E−04
5.7
446
0600–0000
R 3
3469.9960
1.01E−05
10
9.24E−06
8.5
446
0600–0000
R 7
3473.4589
1.71E−05
10
1.62E−05
5.3
446
0600–0000
R 8
3474.3339
1.70E−05
10
1.74E−05
−2.3
446
0600–0000
R 9
3475.2134
1.92E−05
5
1.83E−05
4.7
446
0600–0000
R10
3476.0975
1.80E−05
10
1.89E−05
−5.0
446
0600–0000
R16
3481.4691
1.95E−05
10
1.74E−05
10.8
446
0600–0000
R17
3482.3741
1.80E−05
10
1.64E−05
8.9
446
0600–0000
R22
3486.9380
1.06E−05
5
9.91E−06
6.5
446
0600–0000
R26
3490.6220
5.18E−06
10
4.55E−06
12.2
446
0600–0000
R37
3500.786
4.39E−06
10
4.17E−06
5.0
446
0600–0000
R42
3505.3829
7.40E−05
10
7.46E−05
−0.9
446
0600–0000
R43
3506.2964
1.85E−04
4
1.87E−04
−1.1
446
0600–0000
R44
3507.20805
9.44E−04
2
9.32E−04
1.3
446
0600–0000
R45
3508.15384
1.03E−02
3
1.01E−02
2.0
446
0600–0000
R46
3509.0439
4.40E−04
3
4.50E−04
−2.3
446
0600–0000
R47
3509.9511
1.30E−04
4
1.31E−04
−0.8
446
0600–0000
R48
3510.8590
5.97E−05
4
5.98E−05
−0.2
446
0600–0000
R49
3511.7643
3.25E−05
6
3.30E−05
−1.5
446
0600–0000
R50
3512.6684
2.05E−05
5
2.02E−05
1.5
446
0600–0000
R52
3514.4731
8.21E−06
10
8.99E−06
−9.5
446
0600–0000
R53
3515.3713
5.18E−06
15
6.30E−06
−21.6
446
0600–0000
P 6
3461.636
1.19E−05
10
1.28E−05
−7.6
446
0600–0000
P 7
3460.8247
1.50E−05
10
1.45E−05
3.3
446
0600–0000
P 8
3460.016
1.66E−05
10
1.58E−05
4.8
446
0600–0000
P10
3458.4124
1.82E−05
10
1.78E−05
2.2
446
0600–0000
P26
3446.0616
5.57E−06
10
5.91E−06
−6.1
446
0600–0000
P44
3432.5906
5.35E−05
10
5.19E−05
3.0
446
0600–0000
P46
3431.08092
6.45E−04
4
6.36E−04
1.4
446
0600–0000
P47
3430.35950
6.92E−03
3
6.83E−03
1.3
446
0600–0000
P48
3429.5833
3.00E−04
3
3.02E−04
−0.7
446
0600–0000
P49
3428.8245
8.30E−05
10
8.74E−05
−5.3
446
0620(e)–0000
R23
3496.0399
8.34E−06
10
8.03E−06
3.7
446
0620(e)–0000
R24
3497.0106
1.77E−05
10
1.71E−05
4.5
446
0620(e)–0000
R25
3497.9868
4.33E−05
5
4.40E−05
−1.6
446
0620(e)–0000
R27
3499.95786
1.16E−02
3
1.17E−02
−0.8
446
0620(e)–0000
R28
3500.95643
4.52E−04
3
4.54E−04
−0.4
446
0620(e)–0000
R29
3501.95983
1.11E−04
2
1.09E−04
1.8
446
0620(e)–0000
R32
3505.0130
2.16E−05
5
2.20E−05
−1.9
446
0620(e)–0000
R33
3506.044
1.55E−05
10
1.66E−05
−7.1
446
0620(e)–0000
R34
3507.085
1.40E−05
10
1.31E−05
6.4
446
0620(e)–0000
R35
3508.1315
1.02E−05
10
1.06E−05
−3.9
446
0620(e)–0000
R36
3509.1859
8.25E−06
10
8.84E−06
−7.2
446
0620(e)–0000
R37
3510.2462
7.21E−06
10
7.48E−06
−3.7
446
0620(e)–0000
R38
3511.3154
6.27E−06
10
6.40E−06
−2.1
446
0620(e)–0000
R39
3512.3939
5.77E−06
10
5.56E−06
3.6
446
0620(e)–0000
R41
3514.5690
4.61E−06
10
4.20E−06
8.9
446
0620(e)–0000
R42
3515.6654
3.81E−06
10
3.79E−06
0.5
446
0620(e)–0000
P30
3451.5490
3.58E−04
10
3.60E−04
−0.6
446
0620(e)–0000
P33
3449.566
2.37E−05
10
2.45E−05
−3.4
446
0620(e)–0000
P34
3448.9186
1.70E−05
10
1.68E−05
1.2
446
1001–0000
R27
3500.02968
4.94E−01
3
4.95E−01
−0.2
446
1001–0000
P29
3452.29511
3.98E−01
3
3.99E−01
−0.3
446
1001–0000
R45
3507.99683
4.82E−02
2
4.80E−02
0.5
446
1001–0000
P47
3430.20249
3.32E−02
2
3.25E−02
2.1
446
1111(f)–0110(f)
R57
3504.55976
1.86E−04
3
1.81E−04
2.7
446
1111(f)–0110(f)
P59
3406.5750
1.25E−04
15
1.10E−04
12.0
546
0600–0000
R21
3458.1185
8.00E−06
15
7.10E−06
11.3
546
0600–0000
P23
3421.697
5.86E−06
10
6.18E−06
−5.5
546
0600–0000
R22
3459.0035
1.80E−05
10
1.96E−05
−8.9
546
0600–0000
P24
3420.963
1.50E−05
15
1.69E−05
−12.7
546
0600–0000
R23
3459.8856
1.29E−04
3
1.29E−04
0.0
546
0600–0000
P25
3420.2285
1.01E−04
10
1.09E−04
−7.9
546
0600–0000
R24
3460.807
2.10E−04
10
2.28E−04
−8.5
546
0600–0000
P26
3419.5319
2.00E−04
10
1.92E−04
4.0
546
0600–0000
R25
3461.685
3.11E−05
15
2.76E−05
11.3
546
0600–0000
P27
3418.7944
2.61E−05
15
2.31E−05
11.5
546
0600–0000
R26
3462.578
9.88E−06
546
0600–0000
P28
3418.0706
7.67E−06
10
8.16E−06
−6.4
546
1001–0000
R23
3460.10231
2.35E−03
3
2.34E−03
0.4
546
1001–0000
P25
3420.44553
2.04E−03
3
1.99E−04
2.5
546
1001–0000
R24
3460.63377
2.10E−03
2
2.11E−03
−0.5
Positions in cm−1; strengths in cm−2/atm; % Obs is the estimated uncertainty in the measured line strength; observed-minus-calculated (O – C) is the percent difference between the observed and computed line strength; measurements taken at 296 K.
Bands and lines—14N216O: 0600–0000, 0620(e)–0000, 0710(f)–0110(f),0730(e)–0110(e), and 0730(f)–0110(f); 15N14N16O: 0600–0000 and 1001–0000. Lines—14N216O: R27, R29, R45, and P47 of the 1001–0000 band; R57 and P59 of the 1111(f)–0110(f) band.
Table 17
Values of Observed-minus-Computed Line Positions and Computed Values of These Differences δa for Strongly Perturbed Transitions in Bands of 14N216O and 15N14N16Ob
Observed-minus-computed (O – C) and computed differences (from perturbation theory) Δ in cm−1 × 105. 14N216O: 1001–0000 and 1111(f)–0110(f); 15N14N16O: 1001–0000.
In cm−1, taken from Ref. 4.
δ (cm−1) is the frequency difference between the two interacting upper state levels given in Ref. 4.
Tables (17)
Table 1
Summary of Experimental Conditions
Sample Path Length (m)
Sample Pressure (Torr)
Sample Temperature (K)
Spectral Range (cm−1)
Unapodized Resolution (cm−1)
0.0274
4.90
296
700–2800
0.0058
0.0274
11.67
296
700–2800
0.0058
0.0365
0.844
301
800–2480
0.0054
0.0365
5.13
301
800–2480
0.0054
0.0365
9.02
301
800–2480
0.0054
73.0
1.003
296
800–2200
0.0054
73.0
4.043
296
800–4000
0.0058
1.50
0.1145
296
1800–5600
0.011
1.50
1.009
296
1800–5600
0.011
25.0
1.00
296
1800–5600
0.011
97.0
1.00
296
1800–5600
0.011
434.0
1.00
296
1800–5600
0.011
1.50
10.02
296
1800–5600
0.011
1.50
50.0
296
1800–5600
0.011
1.50
99.7
296
1800–5600
0.011
1.50
301.1
296
1800–5600
0.011
1.50
401.7
296
1800–5600
0.011
1.50
503.7
296
1800–5600
0.011
Isotopic abundances, vibrational QV and rotational QR partition functions at 296 K for N2O
Used in measurements of N2O self-broadened linewidths and collision-induced frequency line shifts.
Asterisk denotes lines used in analysis to determine smoothed values of self-broadening coefficients for the 446 molecule. Plus sign denotes lines used in analysis to determine smoothed values of the 448 molecule linewidth coefficients broadened by 446 molecules.
Table 3
Smoothed Values of Self-broadening Coefficients b∘ of N2O Derived from Measurements
b∘ in cm−1 × 104; measurements taken at 296 K.
Values given in Ref. 9; measurements taken at 295 K.
Percent difference between the value obtained in this work for molecular species 446 and that of Lacome et al. given in Ref. 9.
Table 4
Observed Pressure-Shift Constants d∘ for Self-Broadened N2O
|m|
Line
d∘
Zero Pressure Position
Band
Mol
1
P 1
−1.3
2321.7351
0400–0000
446
2
R 1
−0.8
1881.9325
1110(e)–0000
446
3
R 2
−0.6
1882.7612
1110(e)–0000
446
5
P 5
−0.2
1876.0448
1110(e)–0000
446
9
R 8
−0.6
1887.6683
1110(e)–0000
446
10
P10
−0.5
1871.7471
1110(e)–0000
446
11
P11
−1.6
2299.8989
0510(e)–0110(e)
446
11
P11
−1.3
2300.0336
0510(f)–0110(f)
446
11
P11
−1.2
2285.4478
0400–0000
448
12
P12
−1.3
2299.0754
0510(e)–0110(e)
446
12
P12
−1.3
2299.2389
0510(f)–0110(f)
446
12
P12
−0.8
2284.6830
0400–0000
448
13
P13
−1.7
2298.2532
0510(e)–0110(e)
446
13
P13
−1.4
2298.4483
0510(f)–0110(f)
446
13
P13
−1.6
2401.0708
1200–0000
448
14
R13
−1.5
1891.6715
1110(e)–0000
446
14
P14
−1.3
2297.6617
0510(f)–0110(f)
446
14
R13
−1.7
2334.6316
0400–0000
446
15
P15
−1.1
2399.4360
1200–0000
448
15
R14
−2.0
2321.7779
0510(e)–0110(e)
446
16
R15
−0.7
1893.2507
1110(e)–0000
446
16
P16
−1.4
2295.7942
0510(e)–0110(e)
446
16
P16
−1.7
2296.1004
0510(f)–0110(f)
446
17
R16
−1.9
1894.0356
1110(e)–0000
446
17
P17
−1.3
2295.3257
0510(f)–0110(f)
446
18
P18
−1.5
2294.5548
0510(f)–0110(f)
446
19
R18
−2.0
1895.5959
1110(e)–0000
446
19
P19
−2.0
2279.3909
0400–0000
448
19
P19
−0.3
2396.1424
1200–0000
448
20
R19
−1.8
1896.3713
1110(e)–0000
446
20
P20
−1.5
2293.0247
0510(f)–0110(f)
446
20
P20
−1.5
2278.6432
0400–0000
448
21
R20
−1.5
1897.1436
1110(e)–0000
446
21
P21
−1.1
2292.2653
0510(f)–0110(f)
446
22
R21
−1.8
1897.9126
1110(e)–0000
446
22
P22
−1.3
2291.5097
0510(f)–0110(f)
446
22
P22
−0.5
2393.6506
1200–0000
448
23
R22
−1.5
1898.6785
1110(e)–0000
446
23
P23
−1.2
2290.7577
0510(f)–0110(f)
446
24
R23
−1.9
1899.4412
1110(e)–0000
446
24
P24
−1.7
2391.9790
1200–0000
448
25
P25
−0.4
1858.3989
1110(e)–0000
446
25
R24
−1.3
1900.2007
1110(e)–0000
446
25
P25
−1.2
2391.1400
1200–0000
448
26
R25
−1.5
2345.3744
0400–0000
446
26
P26
−1.0
2390.2988
1200–0000
448
27
P27
−0.6
1856.5682
1110(e)–0000
446
27
P27
−1.4
2286.8647
0510(e)–0110(e)
446
27
P27
−0.9
2389.4555
1200–0000
448
28
P28
−0.4
1855.6483
1110(e)–0000
446
28
P28
−1.5
2300.2197
0400–0000
446
28
P28
−1.4
2286.0588
0510(e)–0110(e)
446
28
P28
−1.3
2287.0516
0510(f)–0110(f)
446
29
P29
−0.9
1854.7256
1110(e)–0000
446
29
R28
−1.7
1903.2069
1110(e)–0000
446
29
P29
−1.5
2299.4556
0400–0000
446
29
P29
−1.5
2285.2537
0510(e)–0110(e)
446
29
R28
−1.3
2335.1126
0510(f)–0110(f)
446
29
P29
−0.4
2387.7621
1200–0000
448
30
P30
−0.8
1853.7998
1110(e)–0000
446
30
R29
−1.8
1903.9505
1110(e)–0000
446
30
R29
−2.0
2349.0110
0400–0000
446
30
P30
−1.3
2284.4493
0510(e)–0110(e)
446
30
P30
−1.5
2285.5930
0510(f)–0110(f)
446
30
P30
−1.6
2386.9121
1200–0000
448
31
P31
−0.5
1852.8712
1110(e)–0000
446
31
R30
−1.9
1904.6908
1110(e)–0000
446
31
P31
−1.5
2297.9316
0400–0000
446
31
R30
−2.0
2349.9229
0400–0000
446
31
P31
−1.3
2284.8687
0510(f)–0110(f)
446
32
P32
−0.4
1851.9395
1110(e)–0000
446
32
R31
−2.1
1905.4280
1110(e)–0000
446
32
R31
−1.5
2350.8358
0400–0000
446
32
P32
−1.6
2284.1474
0510(f)–0110(f)
446
33
P33
−0.4
1851.0050
1110(e)–0000
446
33
R32
−2.6
1906.1619
1110(e)–0000
446
34
P34
−0.9
1850.0675
1110(e)–0000
446
35
P35
−1.0
1849.1270
1110(e)–0000
446
36
P36
−1.5
1848.1837
1110(e)–0000
446
37
P37
−1.1
1847.2374
1110(e)–0000
446
37
R36
−2.3
1909.0656
1110(e)–0000
446
37
R36
−1.8
2364.8366
0420(e)–0000
446
38
P38
−0.5
1846.2882
1110(e)–0000
446
38
P38
−1.5
2279.8820
0510(f)–0110(f)
446
38
R37
−1.7
2365.8331
0420(e)–0000
446
39
R38
−1.3
1910.4980
1110(e)–0000
446
39
P39
−1.8
2279.1806
0510(f)–0110(f)
446
40
P40
−1.3
2291.1239
0400–0000
446
40
R39
−1.3
2358.1566
0400–0000
446
40
P40
−2.3
2278.4818
0510(f)–0110(f)
446
41
P41
−1.9
1843.4233
1110(e)–0000
446
41
R40
−1.5
1911.9176
1110(e)–0000
446
41
P41
−1.2
2290.3705
0400–0000
446
41
P41
−1.7
2277.7853
0510(f)–0110(f)
446
42
P42
−0.6
1842.4626
1110(e)–0000
446
42
P42
−2.9
2123.3596
0111(e)–0110(e)
456
42
P42
−2.7
2123.2647
0111(f)–0110(f)
456
42
R41
−1.9
2345.1953
0510(e)–0110(e)
446
43
P43
−0.5
1841.4989
1110(e)–0000
446
43
R42
−1.7
1913.3243
1110(e)–0000
446
43
P43
−1.3
2288.8642
0400–0000
446
44
P44
−1.5
1840.5324
1110(e)–0000
446
44
P44
−1.3
2288.1112
0400–0000
446
44
R43
−1.5
2361.8180
0400–0000
446
45
P45
−1.3
2287.3582
0400–0000
446
45
P45
−0.4
1839.5631
1110(e)–0000
446
46
P46
−0.4
1838.5909
1110(e)–0000
446
46
P46
−1.5
2286.6051
0400–0000
446
46
R45
−1.4
2363.6462
0400–0000
446
47
P47
−0.5
1837.6158
1110(e)–0000
446
47
P47
−1.5
2285.8519
0400–0000
446
47
R46
−1.7
2364.5595
0400–0000
446
48
P48
−2.2
1836.6379
1110(e)–0000
446
48
P48
−1.3
2285.0984
0400–0000
446
50
P50
−3.0
2114.1826
0111(f)–0110(f)
456
50
R49
−1.9
2367.2949
0400–0000
446
51
R50
−1.5
2368.2052
0400–0000
446
53
P53
−2.6
2110.6717
0111(f)–0110(f)
456
54
P54
−2.4
2122.9995
0001–0000
456
55
R54
−0.8
2504.7519
1200–0000
446
56
P56
−1.8
2120.6119
0001–0000
456
57
P57
−2.1
2119.4085
0001–0000
456
58
P58
−1.7
2118.1987
0001–0000
456
61
P61
−1.8
2114.5310
0001–0000
456
63
P63
−1.8
2112.0541
0001–0000
456
65
P65
−1.1
2403.1525
1200–0000
446
66
P66
−0.5
2402.1553
1200–0000
446
67
P67
−1.4
2401.1546
1200–0000
446
73
R72
−4.2
2266.0319
0001–0000
446
74
R73
−2.5
2266.3487
0001–0000
446
75
R74
−3.0
2266.6584
0001–0000
446
76
R75
−3.0
2266.9608
0001–0000
446
77
R76
−2.4
2267.2561
0001–0000
446
79
R78
−2.5
2267.8252
0001–0000
446
81
R80
−2.8
2268.3655
0001–0000
446
82
R81
−3.3
2268.6248
0001–0000
446
Taken at 296 K; d∘ in cm−2 atm × 103; line positions in cm−1.
Table 5
Band Strengths Sv, Dipole-Moment Matrix Elements |R|, and F Factor Coefficients of N2Oa
Center in cm−1; Sv in cm−2/atm; |R| in debyes; measurements taken at 296 K. Values given within parentheses are estimated uncertainties in the last digit(s). ND denotes not determined.
The standard deviation difference in percent between the computed and measured line strengths for a band. An asterisk denotes a strongly perturbed line (not included in the least-squares analysis). A double asterisk denotes a strongly perturbed band. Analysis included perturbation treatment of interacting levels. F0 and Fxy are interaction parameters involved in the perturbation treatment of the line strengths. Value for Sv is the unperturbed vibrational band strength.
Table 6
Comparison of Studies on Measurements of N2O for the Determination of Band Strengths Sv and F Factor Coefficientsa
Observed-minus-calculated (O – C) strength difference, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 246 K.
Bands: 0200–0000 denoted with asterisk; 1000–0000 denoted with pound.
Table 8
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for Two π − π Bands 111 0(e)–0110(e) and 1110(f)–0110(f) of 14N216O
Observed-minus-calculated (O – C) strengths, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 1110(e)–0110(e) denoted with asterisk; 1110(f)–0110(f) denoted with pound.
Table 9
Computed Values of Line Positions, Line Strengths, Observed-minus-Calculateda Strengths, Results from Measurements of NO2 Samples at High Pressures,b Self-Broadened Half-Widths b∘, and Observed-minus-Smoothed, b∘ for the 1110–0000 and 2000–0110 Bands of 14N216O
Observed-minus-calculated (O – C) values, in percent.
50–504 Torr; positions in cm−1; strengths in cm−2/atm; b∘ in cm−1/atm; measurements taken at 296 K.
Observed-minus-smoothed (O – S) values, in percent. Smoothed values from this work given in Table 3 for 14N216O. Q-branch smoothed values derived from an average between |m| and |m| + 1 smoothed values with J = |m|.
Bands: 1110–0000 denoted with asterisk; 2000–0110 denoted with pound.
Table 10
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for the 0001–0000, 0111(e)–0110(e), and 0111(f)–0110(f) Bands of 14N216Ob
Observed-minus-calculated (O – C) values, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 0001–0000 denoted with asterisk; 0111(e)–0110(e) denoted with plus; 0111(f)–0110(f) denoted with minus.
Table 11
Computed Values of Line Positions, Line Strengths, Observed-minus-Calculateda Strengths, Results from Measurements of Samples at High Pressures,b Self-Broadened Half-Widths b∘, and Observed-minus-Smoothed b∘ for Three 14N216O Bandsc
High Pressure Results
Line
Position
Strength
O – C %
Strength
b∘ × 104
O – S %
*R 0
2323.41432
1.18E−03
2.5
1.20E−03
1240
−2.4
*R 1
2324.25876
2.35E−03
−2.6
2.45E−03
1200
−0.9
*R 2
2325.10639
3.50E−03
−1.2
*R 3
2325.95719
4.61E−03
−3.6
4.70E−03
1155
−0.2
*R 5
2327.66820
6.67E−03
−1.5
*R 6
2328.52835
7.59E−03
1.8
*R 7
2329.39153
8.43E−03
4.3
*R 8
2330.25770
9.18E−03
−1.2
*R 9
2331.12682
9.83E−03
−1.4
*R10
2331.99882
1.04E−02
−1.0
*R11
2332.87365
1.08E−02
0.0
1.08E−02
1035
−0.6
*R12
2333.75124
1.12E−02
3.4
*R13
2334.63153
1.14E−02
−1.8
1.14E−02
1015
−1.4
*R14
2335.51443
1.16E−02
−0.9
*R15
2336.39988
1.16E−02
−0.9
1.16E−02
1008
−0.1
*R16
2337.28778
1.15E−02
0.0
*R17
2338.17806
1.14E−02
0.0
1.15E−02
991
0.4
*R18
2339.07063
1.12E−02
−2.8
1.13E−02
978
−0.3
*R19
2339.96538
1.09E−02
−2.8
*R20
2340.86223
1.06E−02
−3.9
*R21
2341.76108
1.01E−02
−1.0
1.02E−02
970
0.5
*R23
2343.56434
9.21E−03
−2.3
9.33E−03
945
0.1
*R24
2344.46855
8.70E−03
−1.0
*R25
2345.37433
8.18E−03
−2.3
8.20E−03
937
−0.2
*R26
2346.28158
7.64E−03
3.0
*R27
2347.19016
7.10E−03
0.6
7.19E−03
915
−0.2
*R28
2348.09999
6.56E−03
−0.2
*R29
2349.01093
6.03E−03
0.0
6.20E−03
901
0.4
*R30
2349.92287
5.51E−03
6.6
5.62E−03
889
−0.5
*R31
2350.83570
5.02E−03
0.4
5.10E−03
867
−1.0
*R32
2351.74931
4.54E−03
1.3
*R33
2352.66356
4.09E−03
0.3
*R34
2353.57836
3.67E−03
0.8
3.80E−03
885
2.5
*R35
2354.49359
3.27E−03
−8.3
*R36
2355.40913
2.91E−03
2.0
3.04E−03
860
1.7
*R37
2356.32488
2.57E−03
1.9
2.64E−03
840
1.0
*R38
2357.24073
2.26E−03
2.2
*R39
2358.15657
1.98E−03
2.0
1.99E−03
818
−0.9
*R40
2359.07230
1.72E−03
1.7
*R43
2361.81793
1.11E−03
2.6
1.11E−03
785
−3.1
*R45
2363.64617
8.05E−04
3.6
8.25E−04
793
−1.3
*R46
2364.55941
6.82E−04
−1.2
6.85E−04
784
−1.1
*R48
2366.38382
4.83E−04
−1.9
4.83E−04
785
−0.9
*R49
2367.29489
4.04E−04
0.7
4.03E−04
765
−3.1
*R50
2368.20515
3.36E−04
−0.3
3.28E−04
767
−2.7
*R51
2369.11458
2.79E−04
−6.5
*R52
2370.02276
2.30E−04
0.0
2.24E−04
760
−2.1
*R53
2370.92999
1.89E−04
−1.1
*R54
2371.83624
1.55E−04
−3.3
1.53E−04
770
−1.4
*R55
2372.74122
1.26E−04
0.8
*R56
2373.64509
1.02E−04
−6.9
*R57
2374.54821
8.24E−05
−1.7
7.66E−05
760
−1.7
*R58
2375.44972
6.62E−05
−2.6
6.50E−05
780
0.5
*R59
2376.35011
5.30E−05
−3.1
*R60
2377.24925
4.22E−05
−3.2
*R61
2378.14703
3.35E−05
0.0
*R62
2379.04369
2.65E−05
−4.3
*R63
2379.93854
2.08E−05
−4.0
*R64
2380.83199
1.63E−05
−1.9
*R65
2381.72538
1.27E−05
−5.0
*R66
2382.61623
9.87E−06
−4.3
*P 1
2321.73506
1.18E−03
−2.6
1.19E−03
1270
0.0
*P 5
2318.41513
5.56E−03
0.0
*P 6
2317.59314
6.51E−03
−2.0
*P 7
2316.77431
7.38E03
−1.5
*P 8
2315.95862
8.16E−03
0.5
8.25E−03
1088
−1.0
*P10
2314.33650
9.44E−03
0.1
9.48E−03
1073
0.4
*P11
2313.53000
9.93E−03
−2.8
*P12
2312.72647
1.03E−02
−0.0
1.05E−02
1035
−0.6
*P13
2311.92587
1.06E−02
3.6
1.07E−02
1028
−1.1
*P15
2310.33320
1.09E−02
2.7
*P16
2309.54101
1.09E−02
0.0
1.10E−02
1010
0.1
*P17
2308.75150
1.08E−02
−2.9
1.09E−02
991
−0.2
*P18
2307.96458
1.06E−02
−3.9
1.07E−02
985
−0.2
*P19
2307.18019
1.04E−02
−2.0
1.04E−02
975
−0.6
*P20
2306.39824
1.01E−02
−1.0
1.01E−02
974
0.0
*P21
2305.61864
9.69E−03
−1.1
9.70E−03
966
0.1
*P23
2304.06616
8.83E−03
−2.1
*P24
2303.29309
8.36E−03
−0.1
*P25
2302.52201
7.87E−03
−1.8
7.96E−03
951
0.8
*P26
2301.75282
7.36E−03
−0.6
7.55E−03
943
0.4
*P27
2300.98541
6.85E−03
−1.6
6.95E−03
933
1.1
*P28
2300.21969
6.34E−03
−0.2
6.40E−03
915
−0.2
*P29
2299.45555
5.83E−03
−0.5
5.84E−03
900
−1.0
*P30
2298.69289
5.34E−03
0.0
*P31
2297.93159
4.86E−03
−1.3
4.90E−03
890
−0.3
*P32
2297.17156
4.41E−03
−0.2
4.42E−03
870
−0.7
*P33
2296.41267
3.97E−03
3.4
*P34
2295.65484
3.57E−03
−0.9
*P35
2294.89794
3.18E−03
2.2
*P36
2294.14187
2.83E−03
0.7
*P37
2293.38654
2.50E−03
2.7
*P38
2292.63182
2.20E−03
1.3
*P39
2291.87763
1.93E−03
0.0
1.94E−03
827
−0.4
*P40
2291.12387
1.68E−03
−3.7
1.68E−03
815
−1.2
*P41
2290.37043
1.46E−03
0.0
1.46E−03
815
−1.0
*P42
2289.61723
1.26E−03
−1.6
1.27E−03
810
−1.2
*P43
2288.86418
1.08E−03
2.7
1.09E−03
805
−1.6
*P44
2288.11119
9.26E−04
5.5
9.33E−04
799
−1.3
*P45
2287.35819
7.88E−04
1.5
7.91E−04
797
−1.3
*P46
2286.60510
6.69E−04
−0.6
6.70E−04
797
−0.8
*P47
2285.85185
5.64E−04
−0.2
5.67E−04
789
−0.5
*P48
2285.09839
4.74E−04
2.9
4.72E−04
788
−0.4
*P50
2283.59061
3.30E−04
2.4
*P51
2282.83621
2.74E−04
−7.5
*P53
2281.32626
1.86E−04
−1.1
*P54
2280.57027
1.52E−04
6.7
*P55
2279.81379
1.24E−04
−7.8
*P56
2279.05679
1.00E−04
−3.1
*P57
2278.29899
8.11E−05
4.6
*P58
2277.54055
6.52E−05
−1.9
*P59
2276.78187
5.22E−05
−2.8
*P60
2276.02205
4.16E−05
−2.7
*P64
2272.97587
1.61E−05
−5.2
+R 1
2310.72642
2.11E−04
1.9
+R 4
2313.25774
6.51E−04
2.8
+R 5
2314.10416
7.75E−04
−1.0
7.70E−04
1125
−0.1
+R 7
2315.80089
9.93E−04
−1.0
+R 9
2317.50266
1.16E−03
3.3
+R13
2320.92059
1.36E−03
−0.7
+R14
2321.77791
1.38E−03
4.8
1.37E−03
1018
−0.2
+R15
2322.63630
1.38E−03
2.8
+R16
2323.49573
1.38E−03
4.2
1.37E−03
990
−0.3
+R17
2324.35616
1.36E−03
−1.5
1.36E−03
991
0.4
+R18
2325.21755
1.34E−03
0.0
+R19
2326.07988
1.30E−03
0.0
1.32E−03
990
1.6
+R20
2326.94309
1.26E−03
3.1
+R21
2327.80715
1.21E−03
−0.8
+R23
2329.53764
1.10E−03
−1.9
+R25
2331.27104
9.81E−04
−2.1
+R26
2332.13865
9.16E−04
−2.3
+R27
2333.00688
8.52E−04
5.3
8.52E−04
900
−1.9
+R28
2333.87564
7.88E−04
−3.7
+R29
2334.74488
7.25E−04
2.0
+R30
2335.61455
6.63E−04
−0.5
+R32
2337.35501
5.47E−04
−0.9
+R33
2338.22569
4.93E−04
0.0
+R34
2339.09660
4.42E−04
−0.9
+R36
2340.83893
3.51E−04
−2.0
+R37
2341.71025
3.10E−04
−1.6
+R38
2342.58160
2.73E−04
1.1
+R39
2343.45293
2.39E−04
0.4
2.41E−04
840
1.8
+R40
2344.32419
2.08E−04
−1.5
+R41
2345.19534
1.81E−04
−1.6
1.81E−04
820
0.0
+R42
2346.06633
1.56E−04
3.1
+R44
2347.80762
1.15E−04
−3.6
+R46
2349.54769
8.31E−05
−2.6
+R47
2350.41715
7.01E−05
−3.3
+R48
2351.28618
5.90E−05
−1.0
+R49
2352.15404
4.93E−05
4.8
+R50
2353.02213
4.11E−05
0.0
+R51
2353.88928
3.41E−05
−3.0
+R52
2354.75585
2.82E−05
0.0
+R53
2355.62172
2.35E−05
−2.6
+R54
2356.48646
1.90E−05
−1.6
+R59
2360.79887
6.54E−06
1.7
+P 2
2307.37028
2.10E−04
0.9
+P 3
2306.53467
3.68E−04
−0.8
+P 4
2305.70043
5.09E−04
−0.4
+P 5
2304.86756
6.39E−04
0.2
+P 6
2304.03607
7.58E−04
−2.4
+P 7
2303.20594
8.66E−04
−1.5
+P 8
2302.37716
9.63E−04
−0.3
9.57E−04
1100
0.1
+P 9
2301.54973
1.05E−03
−1.0
1.03E−03
1065
−1.4
+P10
2300.72363
1.12E−03
−2.8
1.12E−03
1071
0.2
+P11
2299.89885
1.18E−03
1.7
1.18E−03
1055
0.5
+P12
2299.07539
1.23E−03
0.8
1.24E−03
1032
−0.9
+P13
2298.25321
1.27E−03
−0.8
1.30E−03
1028
−1.1
+P14
2297.43230
1.29E−03
−1.6
1.30E−03
1025
−0.4
+P15
2296.61264
1.30E−03
1.5
1.31E−03
1021
0.1
+P16
2295.79421
1.30E−03
0.0
1.30E−03
1001
−0.8
+P17
2294.97698
1.29E−03
−4.9
+P18
2294.16094
1.27E−03
0.0
+P19
2293.34604
1.24E−03
0.8
+P20
2292.53227
1.21E−03
5.5
+P21
2291.71960
1.17E−03
2.5
1.17E−03
968
0.3
+P22
2290.90799
1.12E−03
−1.8
1.12E−03
966
0.5
+P23
2290.09741
1.06E−03
1.9
+P24
2289.28783
1.01E−03
−3.0
+P25
2288.47921
9.50E−04
2.7
+P26
2287.67153
8.89E−04
−1.4
+P27
2286.86473
8.28E−04
−0.2
8.32E−04
926
0.3
+P28
2286.05878
7.67E−04
−3.9
7.62E−04
915
−0.2
+P29
2285.25366
7.06E−04
−1.6
7.06E−04
911
0.2
+P30
2284.44930
6.47E−04
−0.8
6.44E−04
899
0.2
+P31
2283.64569
5.90E−04
−1.2
+P32
2282.84276
5.35E−04
2.6
+P33
2282.04050
4.83E−04
1.4
+P34
2281.23884
4.34E−04
−3.1
+P35
2280.43776
3.88E−04
−3.5
+P36
2279.63721
3.45E−04
−1.2
+P37
2278.83715
3.05E−04
3.8
+P38
2278.03753
2.69E−04
0.4
+P39
2277.23832
2.36E−04
0.4
+P40
2276.43947
2.06E−04
−5.1
+P41
2275.64094
1.79E−04
−2.3
+P42
2274.84269
1.54E−04
−1.3
+P44
2273.24687
1.14E−04
−0.9
+P45
2272.44923
9.70E−05
−1.3
+P46
2271.65170
8.24E−05
0.8
+P47
2270.85426
6.96E−05
−0.7
+P48
2270.05687
5.85E−05
−0.2
+P49
2269.25950
4.90E−05
2.8
+P50
2268.46210
4.09E−05
3.1
+P51
2267.66425
3.39E−05
−0.6
+P52
2266.86646
2.80E−05
−2.6
+P53
2266.06849
2.31E−05
3.8
+P54
2265.27038
1.89E−05
−0.5
−R 1
2310.73783
2.14E−04
−0.9
−R 2
2311.59016
3.77E−04
3.1
−R 3
2312.44660
5.24E−04
3.9
−R 4
2313.30713
6.60E−04
−2.0
−R 5
2314.17174
7.86E−04
−4.5
7.87E−04
1130
0.4
−R 6
2315.04042
9.02E−04
−1.8
−R 7
2315.91314
1.01E−03
−3.8
9.78E−04
1095
−0.4
−R 8
2316.78988
1.10E−03
3.5
−R 9
2317.67062
1.18E−03
4.8
−R10
2318.55532
1.25E−03
0.0
−R11
2319.44396
1.30E−03
−1.6
−R12
2320.33650
1.35E−03
0.7
1.34E−03
1035
−0.4
−R14
2322.13317
1.39E−03
−1.5
1.39E−03
1010
−1.0
−R16
2323.94502
1.39E−03
−1.5
1.39E−03
998
0.5
−R18
2325.77169
1.35E−03
−3.1
1.35E−03
985
0.4
−R19
2326.69047
1.32E−03
−3.1
−R20
2327.61281
1.28E−03
−0.8
−R21
2328.53866
1.23E−03
1.6
−R22
2329.46796
1.17E−03
1.7
−R24
2331.33665
1.05E−03
−1.0
−R25
2332.27593
9.90E−04
2.0
−R26
2333.21839
9.25E−04
−1.6
9.26E−04
923
0.0
−R21
2334.16398
8.60E−04
−4.4
−R28
2335.11262
7.95E−04
4.2
8.23E−04
905
−0.4
−R30
2337.01874
6.68E−04
1.6
6.80E−04
893
0.0
−R31
2337.97606
6.08E−04
−2.5
6.27E−04
883
0.8
−R32
2338.93610
5.51E−04
1.6
−R33
2339.89879
4.96E−04
−3.1
−R35
2341.83171
3.97E−04
−1.0
−R36
2342.80176
3.52E−04
8.3
−R31
2343.77406
3.11E−04
−2.3
3.15E−04
831
−0.1
−R38
2344.74852
2.74E−04
−0.4
2.70E−04
815
−1.8
−R39
2345.72503
2.39E−04
0.4
−R40
2346.70348
2.09E−04
3.2
2.11E−04
820
−0.4
−R44
2350.63436
1.15E−04
0.9
−R45
2351.62075
9.76E−05
7.0
−R49
2355.57713
4.90E−05
1.4
−R50
2356.56870
4.08E−05
−2.3
−R51
2357.56048
3.38E−05
4.0
−R52
2358.55277
2.79E−05
1.4
−R57
2363.51594
9.99E−06
−5.0
−R58
2364.50744
8.03E−06
−3.5
−R59
2365.49837
6.42E−06
0.3
−R60
2366.48819
5.12E−06
1.9
−P 2
2307.36981
2.12E−04
−2.4
−P 3
2306.53816
3.73E−04
−1.4
−P 4
2305.71065
5.15E−04
0.8
−P 5
2304.88727
6.46E−04
0.0
−P 7
2303.25293
8.76E−04
−1.9
−P 8
2302.44194
9.73E−04
−3.5
9.63E−04
1105
0.5
−P 9
2301.63506
1.06E−03
8.6
1.06E−03
1077
−0.3
−P10
2300.83227
1.13E−03
−2.7
1.13E−03
1081
1.1
−P11
2300.03356
1.19E−03
−1.7
1.18E−03
1055
0.5
−P12
2299.23890
1.24E−03
3.1
1.24E−03
1034
−0.7
−P13
2298.44828
1.28E−03
0.0
1.27E−03
1025
−1.4
−P14
2297.66168
1.30E−03
−1.6
1.30E−03
1027
−0.2
−P15
2296.87906
1.31E−03
1.5
−P16
2296.10040
1.31E−03
1.5
1.31E−03
1005
−0.4
−P17
2295.32567
1.30E−03
−0.8
1.30E−03
995
0.2
−P18
2294.55483
1.28E−03
0.8
1.27E−03
983
−0.4
−P19
2293.78786
1.25E−03
−0.8
−P20
2293.02470
1.21E−03
0.0
1.23E−03
975
0.1
−P21
2292.26533
1.17E−03
0.9
1.17E−03
963
−0.2
−P22
2291.50969
1.12E−03
0.9
1.12E−03
955
−0.6
−P23
2290.75774
1.07E−03
1.8
1.07E−03
957
0.3
−P24
2290.00943
1.01E−03
1.0
1.01E−03
940
−0.4
−P27
2287.78585
8.27E−04
−2.1
−P28
2287.05157
7.65E−04
−0.7
7.65E−04
916
−0.1
−P29
2286.32066
7.04E−04
0.9
7.10E−04
901
−0.9
−P30
2285.59304
6.45E−04
−4.4
6.42E−04
890
−0.8
−P31
2284.86865
5.87E−04
−0.3
5.87E−04
886
−0.8
−P32
2284.14741
5.32E−04
3.4
5.35E−04
877
0.1
−P33
2283.42926
4.80E−04
−1.5
4.81E−04
855
−1.2
−P34
2282.71412
4.31E−04
−0.9
−P35
2282.00190
3.84E−04
−1.1
−P36
2281.29253
3.42E−04
−0.6
−P37
2280.58592
3.02E−04
−2.0
−P38
2279.88198
2.66E−04
5.3
2.69E−04
825
−0.9
−P39
2279.18062
2.33E−04
3.7
2.37E−04
835
0.6
−P40
2278.48175
2.03E−04
3.8
2.02E−04
825
0.0
−P41
2277.78527
1.76E−04
2.8
1.76E−04
828
0.6
−P42
2277.09108
1.52E−04
5.6
−P44
2275.70913
1.12E−04
−1.8
−P46
2274.33505
8.06E−05
−2.9
−P47
2273.65068
6.81E−05
0.9
−P48
2272.96792
5.72E−05
5.1
−P49
2272.28665
4.78E−05
−2.8
−P51
2270.92808
3.30E−05
−1.5
−P52
2270.25097
2.72E−05
−2.2
−P57
2266.87704
9.77E−06
−5.5
50–504 Torr; positions in cm−1; strengths in cm−2/atm; b∘ in cm−1/atm; measurements taken at 296 K.
Observed-minus-smoothed (O – S) values, in percent; smoothed values for 14N216O given in Table 3.
Bands: 0400–0000 denoted with asterisk; 0510(e)–0110(e) denoted with plus; 0510(f)–0110(f) denoted with minus.
Table 12
Computed Values of Line Positions, Line Strengths and Observed-minus-Calculateda Strengths, for the 1200–0000, 1310(e)–0110(e), and 1310(f)–0110(f) Bands of 14N216Ob
Observed-minus-calculated (O – C) values, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 1200–0000 denoted with asterisk; 1310(e)–0110(e) denoted with plus; 1310(f)–0110(f) denoted with minus.
Table 13
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for Bands of 14N216Ob 2000–0000, 2110(e)–0110(e), and 2110(f)–0110(f)
Line
Position
Strength
O– C%
*R 0
2564.17065
6.11E−02
1.8
*R 1
2564.99505
1.22E−01
0.0
*R 2
2565.81262
1.81E−01
−0.6
*R 3
2566.62338
2.39E−01
1.8
*R 4
2567.42731
2.94E−01
0.5
*R 5
2568.22441
3.46E−01
0.5
*R 6
2569.01468
3.94E−01
1.2
*R 7
2569.79812
4.37E−01
0.0
*R 8
2570.57473
4.76E−01
0.9
*R 9
2571.34450
5.10E−01
0.2
*R10
2572.10744
5.39E−01
1.0
*R11
2572.86353
5.62E−01
2.1
*R12
2573.61279
5.80E−01
0.0
*R13
2574.35521
5.93E−01
0.9
*R14
2575.09079
6.00E−01
−0.5
*R15
2575.81954
6.03E−01
0.5
*R16
2576.54144
6.00E−01
2.2
*R17
2577.25651
5.93E−01
1.7
*R18
2577.96475
5.82E−01
0.5
*R19
2578.66616
5.67E−01
−0.3
*R20
2579.36073
5.49E−01
1.2
*R21
2580.04848
5.28E−01
0.8
*R22
2580.72940
5.05E−01
1.1
*R23
2581.40350
4.80E−01
−0.5
*R24
2582.07079
4.54E−01
0.0
*R25
2582.73126
4.26E−01
0.3
*R26
2583.38492
3.98E−01
0.8
*R27
2584.03178
3.70E−01
0.6
*R28
2584.67185
3.42E−01
0.7
*R29
2585.30512
3.15E−01
1.5
*R30
2585.93161
2.88E−01
−0.5
*R31
2586.55132
2.62E−01
0.9
*R32
2587.16426
2.37E−01
0.5
*R33
2587.77044
2.14E−01
0.7
*R34
2588.36987
1.92E−01
0.0
*R35
2588.96255
1.71E−01
0.0
*R36
2589.54850
1.52E−01
0.9
*R37
2590.12773
1.34E−01
0.0
*R38
2590.70024
1.18E−01
1.0
*R39
2591.26606
1.03E−01
1.8
*R40
2591.82519
8.99E−02
0.7
*R41
2592.37764
7.80E−02
0.7
*R42
2592.92343
6.73E−02
1.1
*R43
2593.46258
5.79E−02
0.0
*R44
2593.99509
4.95E−02
2.7
*R45
2594.52100
4.21E−02
−0.5
*R46
2595.04030
3.57E−02
0.3
*R47
2595.55302
3.01E−02
−1.0
*R48
2596.05918
2.53E−02
0.8
*R49
2596.55880
2.12E−02
0.7
*R50
2597.05190
1.76E−02
−2.4
*R51
2597.53850
1.46E−02
0.7
*R52
2598.01862
1.21E−02
−0.4
*R54
2598.95952
8.10E−03
0.8
*R56
2599.87480
5.35E−03
−0.7
*R57
2600.32290
4.32E−03
0.3
*R58
2600.76468
3.47E−03
−1.2
*R59
2601.20017
2.78E−03
1.5
*R60
2601.62939
2.22E−03
1.2
*R61
2602.05239
1.76E−03
−3.9
*R62
2602.46919
1.39E−03
−1.3
*R63
2602.87983
1.09E−03
−1.1
*R64
2603.28435
8.56E−04
0.2
*R65
2603.68278
6.68E−04
−0.9
*R66
2604.07517
5.19E−04
0.0
*R67
2604.46156
4.01E−04
−0.7
*R68
2604.84198
3.09E−04
−4.6
*R69
2605.21649
2.37E−04
2.2
*R70
2605.58513
1.81E−04
−3.9
*R71
2605.94794
1.38E−04
−1.1
*R73
2606.65630
7.85E−05
−2.5
*R74
2607.00195
5.90E−05
0.0
*R76
2607.67647
3.28E−05
4.1
*R77
2608.00595
2.44E−05
−5.8
*R81
2609.26769
7.06E−06
−1.7
*R83
2609.86754
3.71E−06
0.9
*R84
2610.15990
2.67E−06
−2.6
*P 1
2562.50142
6.08E−02
−0.5
*P 2
2561.65659
1.21E−01
0.0
*P 3
2560.80496
1.79E−01
0.0
*P 4
2559.94653
2.34E−01
1.2
*P 5
2559.08131
2.87E−01
1.8
*P 6
2558.20931
3.36E−01
−0.5
*P 7
2557.33052
3.81E−01
2.7
*P 8
2556.44496
4.21E−01
−0.2
*P 9
2555.55262
4.56E−01
1.5
*P10
2554.65353
4.87E−01
1.8
*P11
2553.74768
5.12E−01
2.0
*P12
2552.83508
5.31E−01
0.9
*P13
2551.91575
5.46E−01
1.7
*P14
2550.98968
5.55E−01
0.0
*P15
2550.05688
5.59E−01
1.6
*P16
2549.11737
5.59E−01
0.8
*P17
2548.17116
5.54E−01
3.1
*P18
2547.21824
5.45E−01
0.7
*P19
2546.25864
5.32E−01
2.3
*P20
2545.29236
5.16E−01
1.2
*P21
2544.31941
4.97E−01
−0.8
*P22
2543.33981
4.76E−01
0.9
*P23
2542.35356
4.53E−01
−0.1
*P24
2541.36067
4.29E−01
0.4
*P25
2540.36117
4.03E−01
0.8
*P26
2539.35505
3.77E−01
−0.4
*P27
2538.34234
3.51E−01
−0.9
*P28
2537.32304
3.24E−01
−0.6
*P29
2536.29717
2.98E−01
0.7
*P30
2535.26475
2.73E−01
0.5
*P31
2534.22578
2.49E−01
1.9
*P32
2533.18029
2.25E−01
−0.9
*P33
2532.12829
2.03E−01
−0.9
*P34
2531.06979
1.82E−01
0.0
*P35
2530.00481
1.62E−01
−0.8
*P36
2528.93338
1.44E−01
0.0
*P37
2527.85550
1.27E−01
0.5
*P38
2526.77119
1.12E−01
1.8
*P39
2525.68048
9.81E−02
0.8
*P40
2524.58338
8.55E−02
−0.1
*P41
2523.47992
7.41E−02
0.6
*P42
2522.37011
6.40E−02
0.4
*P43
2521.25398
5.50E−02
−1.0
*P44
2520.13155
4.70E−02
0.5
*P45
2519.00284
4.00E−02
−0.2
*P46
2517.86788
3.39E−02
1.8
*P47
2516.72668
2.86E−02
1.8
*P48
2515.57928
2.40E−02
−0.9
*P49
2514.42571
2.01E−02
0.1
*P50
2513.26598
1.67E−02
−0.7
*P51
2512.10013
1.39E−02
−0.3
*P52
2510.92818
1.14E−02
1.5
*P53
2509.75017
9.39E−03
−1.1
*P54
2508.56613
7.68E−03
−0.3
*P55
2507.37608
6.25E−03
−0.7
*P56
2506.18007
5.07E−03
−0.5
*P57
2504.97812
4.09E−03
−0.4
*P58
2503.77027
3.29E−03
−0.4
*P59
2502.55656
2.63E−03
0.0
*P60
2501.33702
2.10E−03
−1.6
*P62
2498.88061
1.31E−03
−1.6
*P63
2497.64382
1.03E−03
0.9
*P64
2496.40137
8.08E−04
−2.2
*P65
2495.15330
6.30E−04
−3.2
*P66
2493.89965
4.89E−04
0.2
*P67
2492.64047
3.78E−04
−5.6
*P68
2491.37581
2.91E−04
−2.8
*P70
2488.83024
1.70E−04
−1.3
*P71
2487.54943
1.30E−04
−1.9
*P72
2486.26336
9.80E−05
−1.2
*P73
2484.97206
7.39E−05
−1.2
*P74
2483.67561
5.54E−05
6.1
*P75
2482.37406
4.14E−05
−7.5
*P76
2481.06747
3.08E−05
−4.5
*P77
2479.75591
2.29E−05
−6.2
*P78
2478.43944
1.69E−05
−2.2
*P79
2477.11813
1.24E−05
−1.5
*P80
2475.79205
9.07E−06
−0.7
*P81
2474.46127
6.61E−06
−3.8
*P82
2473.12588
4.80E−06
−7.8
*P83
2471.78593
3.47E−06
−2.0
+R 1
2578.74246
4.60E−03
0.0
+R 2
2579.56081
8.11E−03
1.3
+R 3
2580.37248
1.13E−02
2.9
+R 4
2581.17748
1.42E−02
1.4
+R 5
2581.97579
1.69E−02
2.3
+R 6
2582.76742
1.94E−02
0.5
+R 7
2583.55236
2.17E−02
2.4
+R 8
2584.33061
2.37E−02
0.5
+R 9
2585.10216
2.54E−02
1.5
+R10
2585.86703
2.69E−02
1.4
+R11
2586.62520
2.81E−02
0.7
+R12
2587.37667
2.90E−02
−0.8
+R13
2588.12145
2.97E−02
4.2
+R14
2588.85953
3.01E−02
2.7
+R15
2589.59091
3.02E−02
3.2
+R16
2590.31559
3.01E−02
1.3
+R17
2591.03358
2.98E−02
3.1
+R18
2591.74487
2.92E−02
1.4
+R19
2592.44946
2.85E−02
2.2
+R20
2593.14736
2.76E−02
2.3
+R21
2593.83856
2.65E−02
2.5
+R23
2595.20089
2.41E−02
2.8
+R24
2595.87202
2.28E−02
1.8
+R25
2596.53647
2.14E−02
0.9
+R26
2597.19423
2.00E−02
1.0
+R27
2597.84532
1.86E−02
−0.5
+R29
2599.12746
1.58E−02
1.9
+R30
2599.75853
1.45E−02
1.7
+R31
2600.38294
1.32E−02
1.1
+R32
2601.00069
1.19E−02
0.0
+R33
2601.61178
1.07E−02
1.5
+R34
2602.21623
9.62E−03
0.3
+R35
2602.81404
8.59E−03
1.1
+R36
2603.40521
7.62E−03
0.3
+R37
2603.98976
6.74E−03
−0.3
+R38
2604.56768
5.93E−03
0.6
+R39
2605.13900
5.19E−03
0.4
+R40
2605.70371
4.52E−03
2.2
+R41
2606.26182
3.92E−03
0.0
+R42
2606.81335
3.38E−03
0.0
+R43
2607.35830
2.91E−03
−4.9
+R44
2607.89669
2.49E−03
1.0
+R45
2608.42852
2.12E−03
0.0
+R46
2608.95381
1.79E−03
−1.9
+R47
2609.47257
1.51E−03
0.4
+R49
2610.49053
1.06E−03
−2.2
+R50
2610.98977
8.85E−04
0.6
+R51
2611.48253
7.34E−04
−1.2
+R52
2611.96883
6.05E−04
−2.1
+R53
2612.44868
4.97E−04
−0.5
+R54
2612.92209
4.07E−04
−3.0
+R55
2613.38910
3.31E−04
−1.6
+R56
2613.84970
2.69E−04
−0.6
+R57
2614.30394
2.17E−04
−1.3
+R58
2614.75181
1.74E−04
−1.3
+R59
2615.19335
1.40E−04
1.8
+R60
2615.62857
1.11E−04
1.6
+R61
2616.05750
8.82E−05
−6.1
+R63
2616.89658
5.48E−05
0.0
+R64
2617.30678
4.29E−05
−2.2
+R65
2617.71079
3.35E−05
−5.3
+R66
2618.10863
2.60E−05
−11.1
+R67
2618.50033
2.01E−05
−2.1
+R68
2618.88593
1.55E−05
−0.6
+R69
2619.26546
1.19E−05
−1.5
+R70
2619.63895
9.07E−06
−1.9
+P 2
2575.40238
4.55E−03
−1.2
+P 3
2574.55071
8.00E−03
2.0
+P 4
2573.69239
1.11E−02
−0.5
+P 6
2571.95581
1.64E−02
5.5
+P 8
2570.19269
2.09E−02
−3.3
+P 9
2569.30119
2.27E−02
4.7
+P10
2568.40308
2.43E−02
2.2
+P11
2567.49835
2.55E−02
2.1
+P12
2566.58702
2.66E−02
2.0
+P13
2565.66910
2.73E−02
0.7
+P14
2564.74459
2.78E−02
0.0
+P15
2563.81349
2.80E−02
1.7
+P16
2562.87582
2.80E−02
1.7
+P17
2561.93159
2.78E−02
1.5
+P18
2560.98080
2.73E−02
3.5
+P19
2560.02346
2.67E−02
0.4
Observed-minus-calculated (O – C) values, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 2000–0000 denoted with asterisk; 2110–0110(e) denoted with plus; 2110(f)–0110(f) denoted with minus.
Table 14
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for the Four Δ–∑ Bandsb of 14N216O at 296 K
Observed-minus-calculated (O – C) values, in percent; positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Bands: 0220(e)–0000 denoted with asterisk; 0420(e)–0000 denoted with pound; 1220(e)–0000 denoted with plus; 0221(e)–0000 denoted with minus.
Table 15
Computed Values of Line Positions, Line Strengths, and Observed-minus-Calculated Strengthsa for the 1001–0000, 1111(e)–0110(e), and 1111(f)–0110(f) Bands of 14N216O†
Line
Position
Strength
O – C %
*R 0
3481.64677
8.31E−02
2.6
*R 2
3483.27054
2.46E−01
2.2
*R 3
3484.06674
3.25E−01
1.6
*R 4
3484.85247
3.99E−01
0.9
*R 5
3485.62773
4.70E−01
0.2
*R 6
3486.39251
5.35E−01
0.3
*R 7
3487.14682
5.95E−01
0.0
*R 9
3488.62398
6.94E−01
−0.6
*R10
3489.34684
7.33E−01
−1.2
*R11
3490.05920
7.65E−01
−0.6
*R12
3490.76107
7.90E−01
−1.2
*R13
3491.45244
8.07E−01
−1.0
*R14
3492.13331
8.17E−01
−0.7
*R15
3492.80368
8.21E−01
−0.7
*R16
3493.46354
8.17E−01
−1.4
*R17
3494.11290
8.08E−01
−1.5
*R19
3495.38008
7.73E−01
−1.5
*R20
3495.99790
7.49E−01
−0.6
*R21
3496.60520
7.20E−01
0.2
*R23
3497.78824
6.55E−01
−0.3
*R24
3498.36398
6.19E−01
0.0
*R25a
3498.92920
5.82E−01
−0.2
*R26a
3499.48407
5.44E−01
−0.4
*R27a
3500.02970
5.06E−01
−2.4
*R28a
3500.56140
4.68E−01
0.0
*R29a
3501.08471
4.30E−01
0.6
*R30
3501.59739
3.94E−01
−0.2
*R31
3502.09944
3.59E−01
0.4
*R32
3502.59096
3.25E−01
0.4
*R33
3503.07195
2.93E−01
0.4
*R34a
3503.54264
2.63E−01
1.2
*R35a
3504.00263
2.35E−01
0.2
*R36a
3504.45214
2.08E−01
1.3
*R37a
3504.89111
1.84E−01
0.4
*R38a
3505.31960
1.62E−01
0.6
*R39a
3505.73757
1.42E−01
0.7
*R40a
3506.14522
1.24E−01
1.0
*R41a
3506.54229
1.07E−01
0.6
*R42a
3506.92912
9.28E−02
1.0
*R43a
3507.30600
7.97E−02
−0.3
*R44a
3507.67523
6.83E−02
0.5
*R45a
3507.99683
5.82E−02
−20.6
*R46a
3508.36177
4.93E−02
−0.2
*R47a
3508.69787
4.16E−02
0.4
*R48a
3509.02180
3.50E−02
0.8
*R49a
3509.33502
2.93E−02
−0.3
*R50a
3509.63747
2.44E−02
1.2
*R51a
3509.92930
2.02E−02
0.8
*R52a
3510.21068
1.67E−02
1.7
*R53a
3510.48142
1.37E−02
1.8
*R54a
3510.74181
1.13E−02
1.3
*R55a
3510.99163
9.17E−03
1.6
*R56a
3511.23095
7.44E−03
0.8
*R57a
3511.45974
6.01E−03
0.1
*R58
3511.67822
4.84E−03
0.0
*R59
3511.88609
3.88E−03
0.4
*R61
3512.27051
2.46E−03
0.2
*R62
3512.44707
1.94E−03
−0.1
*R63
3512.61321
1.53E−03
2.0
*R64
3512.76894
1.20E−03
−0.7
*R65
3512.91427
9.36E−04
0.6
*R66
3513.04921
7.28E−04
−0.1
*R67
3513.17377
5.63E−04
0.0
*R68
3513.28795
4.34E−04
0.6
*R69
3513.39178
3.33E−04
1.1
*R70
3513.48526
2.55E−04
1.6
*R71
3513.56840
1.94E−04
4.9
*R72
3513.64122
1.47E−04
−2.8
*R73
3513.70373
1.11E−04
−3.7
*R74
3513.75594
8.34E−05
−4.2
*R75
3513.79787
6.24E−05
1.4
*R76
3513.82954
4.65E−05
−2.0
*R77
3513.85096
3.45E−05
−1.0
*R82
3513.80486
7.31E−06
−7.6
*R84
3513.71528
3.82E−06
8.2
*P 1
3479.98118
8.27E−02
1.3
*P 2
3479.13271
1.64E−01
1.8
*P 3
3478.27380
2.43E−01
1.2
*P 4
3477.40445
3.19E−01
1.1
*P 5
3476.52467
3.90E−01
1.7
*P 6
3475.63447
4.57E−01
0.9
*P 7
3474.73383
5.18E−01
2.9
*P 8
3473.82278
5.73E−01
0.3
*P 9
3472.90132
6.21E−01
−0.1
*P10
3471.96944
6.62E−01
−0.3
*P11
3471.02716
6.96E−01
−0.5
*P12
3470.07448
7.23E−01
−1.4
*P13
3469.11141
7.43E−01
−0.1
*P14
3468.13795
7.55E−01
−1.4
*P15
3467.15411
7.61E−01
1.5
*P16
3466.15989
7.61E−01
−0.8
*P17
3465.15530
7.54E−01
−1.1
*P18
3464.14034
7.42E−01
−0.7
*P19
3463.11502
7.25E−01
−1.1
*P20
3462.07935
7.03E−01
−1.2
*P21
3461.03333
6.78E−01
−1.5
*P22
3459.97697
6.49E−01
−0.6
*P23
3458.91028
6.18E−01
0.5
*P24
3457.83326
5.85E−01
−1.0
*P25
3456.74591
5.50E−01
0.0
*P26
3455.64825
5.15E−01
0.0
*P27a
3454.54028
4.79E−01
−0.6
*P28a
3453.42219
4.43E−01
−0.4
*P29a
3452.29509
4.08E−01
−2.4
*P30a
3451.15430
3.73E−01
0.2
*P31a
3450.00537
3.40E−01
1.4
*P32
3448.84607
3.08E−01
0.9
*P33
3447.67641
2.78E−01
0.0
*P34
3446.49649
2.49E−01
0.7
*P35
3445.30633
2.23E−01
−0.2
*P36a
3444.10615
1.98E−01
−1.4
*P37a
3442.89558
1.75E−01
1.2
*P38a
3441.67483
1.54E−01
0.7
*P39a
3440.44387
1.35E−01
1.6
*P40a
3439.20274
1.17E−01
−0.4
*P41a
3437.95144
1.02E−01
−2.8
*P42a
3436.69015
8.80E−02
−2.1
*P43a
3435.41864
7.57E−02
0.7
*P44a
3434.13724
6.47E−02
0.7
*P45a
3432.84626
5.52E−02
−0.1
*P46a
3431.54801
4.68E−02
−2.8
*P47a
3430.20251
3.95E−02
−18.9
*P48a
3428.90075
3.32E−02
−1.2
*P49a
3427.57055
2.78E−02
−3.6
*P50a
3426.22860
2.31E−02
0.8
*P51a
3424.87635
1.92E−02
3.7
*P52a
3423.51375
1.58E−02
1.7
*P53a
3422.14098
1.30E−02
0.0
*P54a
3420.75819
1.06E−02
2.3
*P55a
3419.36522
8.67E−03i
3.6
*P56a
3417.96236
7.04E−03i
3.6
*P57a
3416.54940
5.68E−03i
0.5
*P58a
3415.12642
4.57E−03i
−1.1
*P59a
3413.69340
3.66E−03i
0.5
*P60
3412.25056
2.92E−03
−0.6
*P61
3410.79761
2.32E−03
0.1
*P62
3409.33474
1.83E−03
0.5
*P63
3407.86194
1.44E−03
−0.8
*P64
3406.37925
1.13E−03
−0.7
*P65
3404.88668
8.82E−04
−0.1
*P67
3401.87196
5.30E−04
−1.2
*P69
3398.81792
3.13E−04
−0.8
*P70
3397.27620
2.39E−04
−2.8
*P72
3394.16348
1.38E−04
−3.0
*P74
3391.01185
7.82E−05
−3.2
*P76
3387.82146
4.36E−05
−2.1
*P79
3382.96363
1.76E−05
−2.8
*P80
3381.32519
1.29E−05
1.6
*P82
3378.01969
6.83E−06
−6.1
*P83
3376.35269
4.94E−06
3.8
+R 1
3474.85767
7.01E−03
0.5
+R 2
3475.66525
1.24E−02
3.3
+R 3
3476.46255
1.72E−02
1.2
+R 4
3477.24959
2.17E−02
2.0
+R 5
3478.02635
2.58E−02
1.9
+R 7
3479.54903
3.30E−02
0.8
+R 8
3480.29495
3.61E−02
−0.3
+R 9
3481.03057
3.88E−02
−2.0
+R10
3481.75591
4.10E−02
−2.0
+R12
3483.17568
4.43E−02
−1.1
+R13
3483.87012
4.53E−02
−0.6
+R14
3484.55425
4.58E−02
1.0
+R15
3485.22808
4.60E−02
−1.4
+R16
3485.89159
4.58E−02
−2.6
+R17
3486.54480
4.53E−02
−1.2
+R18
3487.18769
4.45E−02
2.0
+R19
3487.82027
4.34E−02
0.8
+R20
3488.44253
4.20E−02
−1.9
+R21
3489.05446
4.04E−02
−1.0
+R22
3489.65608
3.86E−02
−1.6
+R23
3490.24738
3.67E−02
−2.0
+R24
3490.82835
3.47E−02
−2.0
+R25
3491.39899
3.26E−02
−0.3
+R26
3491.95931
3.04E−02
−1.5
+R27
3492.50930
2.83E−02
−1.1
+R28
3493.04897
2.62E−02
−0.6
+R29
3493.57830
2.40E−02
1.4
+R30a
3494.09731
2.20E−02
8.7
+R31a
3494.60599
2.00E−02
3.3
+R32a
3495.10444
1.81E−02
1.5
+R33a
3495.59263
1.63E−02
1.0
+R34a
3496.07230
1.46E−02
−3.1
+R35a
3496.53710
1.31E−02
1.1
+R36a
3496.99428
1.16E−02
2.6
+R37a
3497.44115
1.02E−02
1.5
+R38
3497.87753
9.01E−03
0.9
+R39
3498.30359
7.89E−03
−0.2
+R40
3498.71933
6.87E−03
1.3
+R41
3499.12475
5.96E−03
1.2
+R42
3499.51985
5.14E−03
0.7
+R43
3499.90464
4.42E−03
−0.2
+R44
3500.27911
3.78E−03
2.1
+R45
3500.64327
3.22E−03
1.0
+R46
3500.99712
2.73E−03
0.5
+R47
3501.34067
2.30E−03
0.0
+R48
3501.67393
1.93E−03
1.0
+R49
3501.99688
1.61E−03
0.9
+R50
3502.30955
1.34E−03
0.4
+R51
3502.61193
1.11E−03
−9.2
+R52
3502.90402
9.19E−04
−1.0
+R53
3503.18584
7.55E−04
2.6
+R54
3503.45739
6.18E−04
1.2
+R55
3503.71868
5.03E−04
1.0
+R56
3503.96971
4.08E−04
−2.7
+R57
3504.21048
3.29E−04
2.4
+R59a
3504.66169
2.12E−04
3.8
+R60a
3504.87200
1.69E−04
2.0
+R61a
3505.07245
1.34E−04
0.2
+R62a
3505.26262
1.06E−04
0.3
+R63a
3505.44397
8.31E−05
−1.3
+R64a
3505.61778
6.51E−05
−1.1
+R65a
3505.79066
5.08E−05
3.6
+R66a
3505.83450
3.94E−05
−38.4
+R67a
3506.02891
3.05E−05
−52.5
+R68a
3506.16371
2.35E−05
3.8
+R69a
3506.28906
1.80E−05
3.7
+R70a
3506.39813
1.37E−05
1.8
+R71a
3506.49531
1.05E−05
1.4
+P 2
3471.52477
6.95E−03
−0.7
+P 3
3470.66592
1.22E−02
0.0
+P 4
3469.79682
1.69E−02
1.9
+P 5
3468.91749
2.12E−02
2.9
+P 6
3468.02792
2.51E−02
0.4
+P 7
3467.12812
2.87E−02
1.8
+P 8
3466.21811
3.19E−02
2.0
+P 9
3465.29787
3.46E−02
0.1
+P10
3464.36742
3.70E−02
0.0
+P11
3463.42676
3.90E−02
1.2
+P12
3462.47590
4.06E−02
1.0
+P13
3461.51485
4.17E−02
0.7
+P14
3460.54360
4.25E−02
−1.1
+P15
3459.56216
4.28E−02
0.4
+P16
3458.57055
4.28E−02
0.5
+P17
3457.56876
4.24E−02
−3.5
+P18
3456.55680
4.18E−02
−1.4
+P19
3455.53469
4.08E−02
0.5
+P20
3454.50241
3.96E−02
−2.8
+P21
3453.45999
3.81E−02
0.1
+P22
3452.40743
3.65E−02
0.0
+P23
3451.34473
3.48E−02
−2.3
+P24
3450.27190
3.29E−02
1.8
+P25
3449.18895
3.10E−02
5.3
+P26
3448.09588
2.89E−02
1.2
+P27
3446.99271
2.69E−02
−7.7
+P28
3445.87944
2.49E−02
1.2
+P29
3444.75608
2.29E−02
3.3
+P30
3443.62263
2.10E−02
0.0
+P31
3442.47911
1.91E−02
3.5
+P32a
3441.32552
1.73E−02
−0.6
+P33a
3440.16187
1.56E−02
−0.6
+P34a
3438.98828
1.40E−02
−2.1
+P35a
3437.80471
1.25E−02
0.9
+P36a
3436.61291
1.11E−02
0.0
+P37a
3435.40654
9.80E−03
3.0
+P38a
3434.19288
8.62E−03
−0.2
+P39a
3432.96922
7.55E−03
0.7
+P40
3431.73541
6.57E−03
−3.9
+P41
3430.49161
5.70E−03
−2.7
+P43
3427.97409
4.23E−03
−0.2
+P44
3426.70040
3.62E−03
−0.4
+P45
3425.41676
3.08E−03
3.2
+P46
3424.12319
2.61E−03
−1.1
+P47
3422.81971
2.20E−03
−1.0
+P48
3421.50631
1.85E−03
−2.7
+P49
3420.18302
1.55E−03
−2.4
+P50
3418.84984
1.29E−03
1.0
+P51
3417.50679
1.07E−03
−0.6
+P52
3416.15388
8.79E−04
4.4
+P53
3414.79113
7.22E−04
−1.6
+P54
3413.41855
5.91E−04
−2.5
+P55
3412.03615
4.81E−04
1.5
+P58
3407.83018
2.53E−04
−1.9
+P60
3404.97739
1.61E−04
−0.7
+P61a
3403.53677
1.28E−04
−1.4
+P62a
3402.08632
1.01E−04
3.9
+P63a
3400.62653
7.94E−05
3.5
+P64a
3399.15699
6.22E−05
−7.9
+P65a
3397.67917
4.85E−05
−2.7
+P66a
3396.19437
3.76E−05
3.5
+P68a
3393.09557
2.24E−05
3.5
+P70a
3390.11156
1.31E−05
3.7
+P71a
3388.58120
9.96E−06
−2.7
+P72a
3387.03516
7.54E−06
1.9
+P73a
3385.47784
5.68E−06
3.6
−R 1
3474.86135
7.02E−03
0.4
−R 2
3475.67107
1.24E−02
3.3
−R 3
3476.47070
1.72E−02
1.1
−R 4
3477.26025
2.17E−02
1.9
−R 5
3478.03970
2.58E−02
3.7
−R 6
3478.80907
2.96E−02
1.6
−R 7
3479.56834
3.31E−02
−0.5
−R 8
3480.31751
3.61E−02
−0.3
−R 9
3481.05658
3.88E−02
−2.1
−R10
3481.78555
4.10E−02
−0.3
−R11
3482.50442
4.29E−02
0.0
−R12
3483.21318
4.43E−02
−0.2
−R13
3483.91183
4.53E−02
−2.0
−R14
3484.60037
4.58E−02
0.1
−R15
3485.27880
4.60E−02
1.6
−R16
3485.94713
4.58E−02
0.3
−R17
3486.60533
4.53E−02
0.0
−R18
3487.25343
4.45E−02
−1.5
−R20
3488.51929
4.20E−02
−0.8
−R21
3489.13705
4.04E−02
0.4
−R22
3489.74469
3.86E−02
2.1
−R23
3490.34223
3.67E−02
−0.4
−R24
3490.92965
3.46E−02
−1.3
−R25
3491.50697
3.25E−02
−3.0
−R26
3492.07417
3.04E−02
−2.3
−R27
3492.63127
2.82E−02
−3.1
−R28
3493.17827
2.61E−02
0.4
−R29
3493.71516
2.40E−02
0.0
−R30
3494.24196
2.19E−02
−0.6
−R32
3495.26525
1.81E−02
1.8
−R33
3495.76176
1.63E−02
−1.7
−R34a
3496.24836
1.46E−02
0.8
−R35a
3496.72491
1.30E−02
3.6
−R36a
3497.19278
1.15E−02
3.8
−R37a
3497.64600
1.02E−02
−2.0
−R38a
3498.09246
8.97E−03
1.6
−R39a
3498.52873
7.85E−03
0.9
−R40a
3498.95479
6.83E−03
−3.2
−R41a
3499.37077
5.92E−03
0.9
−R42a
3499.77670
5.11E−03
−0.4
−R43
3500.17270
4.39E−03
−0.9
−R45
3500.93424
3.19E−03
0.5
−R46
3501.30022
2.71E−03
0.9
−R47a
3501.65625
2.28E−03
−0.5
−R48a
3502.00210
1.92E−03
0.2
−R49a
3502.33805
1.60E−03
0.5
−R50a
3502.66405
1.33E−03
0.6
−R51a
3502.98002
1.10E−03
3.2
−R52a
3503.28660
9.10E−04
3.1
−R53a
3503.58354
7.48E−04
−2.1
−R54a
3503.87088
6.11E−04
−1.2
−R55a
3504.15100
4.97E−04
0.5
−R56a
3504.42655
4.03E−04
−2.1
−R57a
3504.55976
3.25E−04
−74.9
−R59a
3505.13539
2.09E−04
0.5
−R60a
3505.36502
1.66E−04
−4.0
−R61a
3505.58310
1.32E−04
0.7
−R62a
3505.79077
1.04E−04
3.5
−R63a
3505.98841
8.20E−05
3.0
−R64a
3506.17609
6.42E−05
3.5
−R65a
3506.35372
5.00E−05
2.3
−R66a
3506.523132
3.88E−05
3.4
−R67
3506.67920
3.00E−05
−1.7
−R68
3506.82830
2.31E−05
8.7
−R69
3506.96680
1.77E−05
−11.3
−R73
3507.42450
5.85E−06
−4.5
−R74
3507.51430
4.39E−06
7.0
−R75
3507.59520
3.28E−06
−2.8
−P 2
3471.52175
6.96E−03
−0.8
−P 3
3470.66168
1.22E−02
0.0
−P 4
3469.79155
1.69E−02
1.8
−P 5
3468.91138
2.12E−02
2.8
−P 6
3468.02115
2.51E−02
0.3
−P 7
3467.12089
2.87E−02
1.8
−P 8
3466.21059
3.19E−02
1.9
−P 9
3465.29025
3.47E−02
0.0
−P10
3464.35990
3.71E−02
−0.2
−P11
3463.41952
3.90E−02
1.2
−P12
3462.46913
4.06E−02
1.0
−P13
3461.50874
4.17E−02
0.6
−P14
3460.53835
4.25E−02
−1.1
−P15
3459.55797
4.28E−02
0.4
−P16
3458.56760
4.28E−02
0.5
−P17
3457.56726
4.24E−02
−3.5
−P18
3456.55694
4.17E−02
−1.3
−P19
3455.53667
4.08E−02
0.6
−P20
3454.50644
3.96E−02
−2.7
−P21
3453.46627
3.81E−02
0.2
−P22
3452.41616
3.65E−02
0.0
−P23
3451.35612
3.47E−02
−2.2
−P24
3450.28617
3.29E−02
1.9
−P25
3449.20631
3.09E−02
5.5
−P26
3448.11654
2.89E−02
3.7
−P27
3447.01689
2.69E−02
0.5
−P28
3445.90736
2.49E−02
−0.6
−P29
3444.78795
2.29E−02
−0.3
−P30
3443.65869
2.09E−02
1.3
−P31
3442.51958
1.90E−02
−3.0
−P32
3441.37063
1.73E−02
0.0
−P33
3440.21186
1.55E−02
0.0
−P34
3439.04327
1.39E−02
−1.0
−P35
3437.86487
1.24E−02
1.3
−P36a
3436.67687
1.10E−02
3.1
−P37a
3435.47912
9.76E−03
−0.4
−P38a
3434.27300
8.58E−03
−5.4
−P39a
3433.05257
7.51E−03
0.4
−P40a
3431.82569
6.54E−03
−5.6
−P41a
3430.58897
5.67E−03
−0.3
−P42a
3429.34239
4.89E−03
2.2
−P43a
3428.08609
4.20E−03
0.0
−P44a
3426.82010
3.59E−03
0.8
−P45
3425.54456
3.06E−03
−1.9
−P46
3424.25918
2.59E−03
−2.0
−P47
3422.96417
2.18E−03
−2.1
−P48
3421.65978
1.83E−03
−1.9
−P49a
3420.34586
1.53E−03
−0.8
−P50a
3419.02216
1.28E−03
0.4
−P51a
3417.68901
1.06E−03
−1.6
−P52a
3416.34632
8.71E−04
−7.5
−P53a
3414.99406
7.15E−04
−1.6
−P54a
3413.63286
5.85E−04
−0.3
−P55a
3412.26248
4.76E−04
1.5
−P56a
3410.88296
3.85E−04
0.1
−P57a
3409.49671
3.11E−04
0.6
−P58a
3408.10637
2.50E−04
−5.4
−P59a
3406.57420
2.00E−04
−66.7
−P60a
3405.24018
1.59E−04
−6.0
−P61a
3403.82057
1.26E−04
1.5
−P62a
3402.38635
9.96E−05
3.3
−P63a
3400.94111
7.83E−05
−5.0
−P64a
3399.48600
6.12E−05
−2.1
−P65a
3398.02140
4.77E−05
3.6
−P66a
3396.54740
3.70E−05
11.0
−P67a
3395.06392
2.86E−05
4.6
−P69
3392.06890
1.69E−05
−5.4
−P74
3384.42392
4.18E−06
−1.7
Computed line strengths were calculated from constants given in Table 5 (unperturbed) whereas the computed (unperturbed) line positions were derived from constants given in Ref. 4 and corrected to the “true” values for the perturbed transitions. Line positions in cm−1; strengths in cm−2/atm; measurements taken at 296 K.
Perturbed transitions.
Table 16
Observed Line Positions, Line Strengths, Percent Observed, Observed-minus-Calculated Strengths, and Computed Strengthsa of Perturbed Transitions in Bands and Lines of 14N216O and 15N14N16Ob
Line Strength
Mol
Band
Line
Position
Observed
% Obs
Computed
O – C%
446
0710(f)–0110(f)
R56
3503.6643
7.00E−06
10
7.22E−06
−3.1
446
0710(f)–0110(f)
P58
3407.3443
6.18E−06
15
4.44E−06
28.2
446
0710(f)–0110(f)
R57
3504.8095
1.43E−04
4
1.44E−04
−0.7
446
0710(f)–0110(f)
P59
3406.8242
8.99E−05
8
8.79E−05
2.2
446
0730(f)–0110(f)
R36
3497.04547
1.68E−04
3
1.84E−04
−9.5
446
0730(f)–0110(f)
P38
3434.1260
1.49E−04
10
1.36E−04
8.7
446
0730(f)–0110(f)
R37
3498.0315
3.06E−05
4
2.99E−05
2.3
446
0730(f)–0110(f)
P39
3433.436
1.88E−05
10
2.22E−05
−18.1
446
0730(e)–0110(e)
R34
3495.992
4.01E−04
10
4.01E−04
0.0
446
0730(e)–0110(e)
P36
3436.533
3.24E−04
10
3.05E−04
5.7
446
0600–0000
R 3
3469.9960
1.01E−05
10
9.24E−06
8.5
446
0600–0000
R 7
3473.4589
1.71E−05
10
1.62E−05
5.3
446
0600–0000
R 8
3474.3339
1.70E−05
10
1.74E−05
−2.3
446
0600–0000
R 9
3475.2134
1.92E−05
5
1.83E−05
4.7
446
0600–0000
R10
3476.0975
1.80E−05
10
1.89E−05
−5.0
446
0600–0000
R16
3481.4691
1.95E−05
10
1.74E−05
10.8
446
0600–0000
R17
3482.3741
1.80E−05
10
1.64E−05
8.9
446
0600–0000
R22
3486.9380
1.06E−05
5
9.91E−06
6.5
446
0600–0000
R26
3490.6220
5.18E−06
10
4.55E−06
12.2
446
0600–0000
R37
3500.786
4.39E−06
10
4.17E−06
5.0
446
0600–0000
R42
3505.3829
7.40E−05
10
7.46E−05
−0.9
446
0600–0000
R43
3506.2964
1.85E−04
4
1.87E−04
−1.1
446
0600–0000
R44
3507.20805
9.44E−04
2
9.32E−04
1.3
446
0600–0000
R45
3508.15384
1.03E−02
3
1.01E−02
2.0
446
0600–0000
R46
3509.0439
4.40E−04
3
4.50E−04
−2.3
446
0600–0000
R47
3509.9511
1.30E−04
4
1.31E−04
−0.8
446
0600–0000
R48
3510.8590
5.97E−05
4
5.98E−05
−0.2
446
0600–0000
R49
3511.7643
3.25E−05
6
3.30E−05
−1.5
446
0600–0000
R50
3512.6684
2.05E−05
5
2.02E−05
1.5
446
0600–0000
R52
3514.4731
8.21E−06
10
8.99E−06
−9.5
446
0600–0000
R53
3515.3713
5.18E−06
15
6.30E−06
−21.6
446
0600–0000
P 6
3461.636
1.19E−05
10
1.28E−05
−7.6
446
0600–0000
P 7
3460.8247
1.50E−05
10
1.45E−05
3.3
446
0600–0000
P 8
3460.016
1.66E−05
10
1.58E−05
4.8
446
0600–0000
P10
3458.4124
1.82E−05
10
1.78E−05
2.2
446
0600–0000
P26
3446.0616
5.57E−06
10
5.91E−06
−6.1
446
0600–0000
P44
3432.5906
5.35E−05
10
5.19E−05
3.0
446
0600–0000
P46
3431.08092
6.45E−04
4
6.36E−04
1.4
446
0600–0000
P47
3430.35950
6.92E−03
3
6.83E−03
1.3
446
0600–0000
P48
3429.5833
3.00E−04
3
3.02E−04
−0.7
446
0600–0000
P49
3428.8245
8.30E−05
10
8.74E−05
−5.3
446
0620(e)–0000
R23
3496.0399
8.34E−06
10
8.03E−06
3.7
446
0620(e)–0000
R24
3497.0106
1.77E−05
10
1.71E−05
4.5
446
0620(e)–0000
R25
3497.9868
4.33E−05
5
4.40E−05
−1.6
446
0620(e)–0000
R27
3499.95786
1.16E−02
3
1.17E−02
−0.8
446
0620(e)–0000
R28
3500.95643
4.52E−04
3
4.54E−04
−0.4
446
0620(e)–0000
R29
3501.95983
1.11E−04
2
1.09E−04
1.8
446
0620(e)–0000
R32
3505.0130
2.16E−05
5
2.20E−05
−1.9
446
0620(e)–0000
R33
3506.044
1.55E−05
10
1.66E−05
−7.1
446
0620(e)–0000
R34
3507.085
1.40E−05
10
1.31E−05
6.4
446
0620(e)–0000
R35
3508.1315
1.02E−05
10
1.06E−05
−3.9
446
0620(e)–0000
R36
3509.1859
8.25E−06
10
8.84E−06
−7.2
446
0620(e)–0000
R37
3510.2462
7.21E−06
10
7.48E−06
−3.7
446
0620(e)–0000
R38
3511.3154
6.27E−06
10
6.40E−06
−2.1
446
0620(e)–0000
R39
3512.3939
5.77E−06
10
5.56E−06
3.6
446
0620(e)–0000
R41
3514.5690
4.61E−06
10
4.20E−06
8.9
446
0620(e)–0000
R42
3515.6654
3.81E−06
10
3.79E−06
0.5
446
0620(e)–0000
P30
3451.5490
3.58E−04
10
3.60E−04
−0.6
446
0620(e)–0000
P33
3449.566
2.37E−05
10
2.45E−05
−3.4
446
0620(e)–0000
P34
3448.9186
1.70E−05
10
1.68E−05
1.2
446
1001–0000
R27
3500.02968
4.94E−01
3
4.95E−01
−0.2
446
1001–0000
P29
3452.29511
3.98E−01
3
3.99E−01
−0.3
446
1001–0000
R45
3507.99683
4.82E−02
2
4.80E−02
0.5
446
1001–0000
P47
3430.20249
3.32E−02
2
3.25E−02
2.1
446
1111(f)–0110(f)
R57
3504.55976
1.86E−04
3
1.81E−04
2.7
446
1111(f)–0110(f)
P59
3406.5750
1.25E−04
15
1.10E−04
12.0
546
0600–0000
R21
3458.1185
8.00E−06
15
7.10E−06
11.3
546
0600–0000
P23
3421.697
5.86E−06
10
6.18E−06
−5.5
546
0600–0000
R22
3459.0035
1.80E−05
10
1.96E−05
−8.9
546
0600–0000
P24
3420.963
1.50E−05
15
1.69E−05
−12.7
546
0600–0000
R23
3459.8856
1.29E−04
3
1.29E−04
0.0
546
0600–0000
P25
3420.2285
1.01E−04
10
1.09E−04
−7.9
546
0600–0000
R24
3460.807
2.10E−04
10
2.28E−04
−8.5
546
0600–0000
P26
3419.5319
2.00E−04
10
1.92E−04
4.0
546
0600–0000
R25
3461.685
3.11E−05
15
2.76E−05
11.3
546
0600–0000
P27
3418.7944
2.61E−05
15
2.31E−05
11.5
546
0600–0000
R26
3462.578
9.88E−06
546
0600–0000
P28
3418.0706
7.67E−06
10
8.16E−06
−6.4
546
1001–0000
R23
3460.10231
2.35E−03
3
2.34E−03
0.4
546
1001–0000
P25
3420.44553
2.04E−03
3
1.99E−04
2.5
546
1001–0000
R24
3460.63377
2.10E−03
2
2.11E−03
−0.5
Positions in cm−1; strengths in cm−2/atm; % Obs is the estimated uncertainty in the measured line strength; observed-minus-calculated (O – C) is the percent difference between the observed and computed line strength; measurements taken at 296 K.
Bands and lines—14N216O: 0600–0000, 0620(e)–0000, 0710(f)–0110(f),0730(e)–0110(e), and 0730(f)–0110(f); 15N14N16O: 0600–0000 and 1001–0000. Lines—14N216O: R27, R29, R45, and P47 of the 1001–0000 band; R57 and P59 of the 1111(f)–0110(f) band.
Table 17
Values of Observed-minus-Computed Line Positions and Computed Values of These Differences δa for Strongly Perturbed Transitions in Bands of 14N216O and 15N14N16Ob
Observed-minus-computed (O – C) and computed differences (from perturbation theory) Δ in cm−1 × 105. 14N216O: 1001–0000 and 1111(f)–0110(f); 15N14N16O: 1001–0000.
In cm−1, taken from Ref. 4.
δ (cm−1) is the frequency difference between the two interacting upper state levels given in Ref. 4.