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Trace detection of N2 by KrF-laser-excited spontaneous Raman spectroscopy

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Abstract

A 100-mJ/pulse 10-Hz KrF laser has been used for pulsed-UV-excited vibrational Raman spectroscopy. Gated photon counting techniques were used to detect Raman signals that were linear for N2 partial pressures between 10−4 and 2 × 10−3 Torr. Single-shot Raman signals were linear for N2 partial pressures between 0.5 and 600 Torr. No interferences from laser-induced nonlinear effects were observed.

© 1981 Optical Society of America

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